The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Prussian blue is also known, as we have said, as Chinese blue, Berlin
blue and Paris blue; Brunswick blue or mineral blue is another form.
Generally the product under the name of Chinese or Paris blue,
which has an intense dark blue colour, is quite pure, whilst under
the names of Prussian blue and Berlin blue mixtures with starch or
alumina are included, which consequently have a more or less pale
colour. The pigments known as mineral or Brunswick blue are the
least valuable, they have generally a less deep colour and are quite
without the metallic lustre which distinguishes Chinese blue and the
better varieties of Prussian blue. Mineral blue often contains very
large quantities of alumina, chalk, or even barytes; the addition of
the last is to be regarded as irrational, since it makes the pigment
conspicuously heavy.
=Chinese Blue.=—Pure Chinese blue appears in the form of deep blue
masses, characterised by a peculiar metallic lustre, which is
especially marked when the surface of a lump is rubbed with the finger
nail. This metallic lustre is accompanied by a copper-red shimmer
which is similar to that exhibited by fine indigo. In large pieces
pure Chinese blue appears very dark by artificial light; it possesses
enormous strength of colour. The following test serves for the
recognition of the complete purity of Chinese blue: A small quantity
is powdered and rubbed in a thin layer on white paper; if the metallic
lustre shows in undiminished strength the blue may be regarded as quite
pure, for Chinese blue quickly loses this property by additions of
other substances.
From what has been said above concerning the different behaviour of
ferrous and ferric salts, the simplest method of making Chinese blue
would be to precipitate the solution of a ferric salt with yellow
prussiate, keeping the ferric salt in excess, to wash and dry the
precipitate. Ferric salts are, however, dearer than ferrous salts, so
that the latter are generally used.
In making Chinese blue from a ferrous salt ferrous sulphate or green
vitriol is generally taken. This salt is dissolved in water; it is
advisable to add a small quantity of sulphuric acid, since the water
will contain carbonates, which produce ferrous carbonate. Air oxidises
the latter to ferric hydroxide, which is brown, and if present even
in small quantity will spoil the shade of the blue. This addition of
sulphuric acid is of special importance when the white precipitate
produced by the prussiate solution is to be oxidised by the air.
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