The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
A solution of yellow prussiate is added to the iron solution in such
quantity that a very small excess of iron salt is left; there results
a white or rather, since the ferrous sulphate always contains small
quantities of ferric oxide, a pale blue precipitate. This is allowed
to settle, the liquid drawn off as completely as possible from the
precipitate, and nitric acid then added, or a solution of bleaching
powder, followed by the amount of sulphuric acid required to decompose
it. The nitric acid or the chlorine liberated from the bleaching powder
speedily effects the oxidation, changing the pale blue colour to the
deep blue of Chinese blue. The precipitate should be left for several
days in contact with the liquid in order to complete the oxidation;
it is then well washed and dried. Pieces of definite shape and size
bearing the trade mark of the firm are often pressed from the blue when
it has acquired a stiff consistency.
There are many formulæ for the preparation of Chinese blue, differing
in regard to the quantities of green vitriol, yellow prussiate, and
nitric acid or bleaching powder to be used. It is, however, clear
that only _one_ formula can be correct, that in which the quantities
of materials are equivalent, since the reactions take place between
equivalent quantities. In practice the equivalent quantities would not
be weighed to the tenth of a gramme—there would be no object in such a
proceeding, since in works chemically pure substances are not used; but
manufacturers should work according to equivalent quantities in order
to use up their materials as completely as possible. No increase in
labour is involved, the same labour weighs one or another quantity.
The proportion of materials in which the least loss is involved is here
given. Nine kilogrammes of green vitriol are dissolved in 100 litres of
water, 15 kilogrammes of strong sulphuric acid are added, and then a
solution of 15 kilogrammes of yellow prussiate in 100 litres of water.
The solutions are kept in constant motion during the mixing. As soon
as the decomposition is finished, without waiting for the precipitate
to settle, steam is led in and 20 kilogrammes of nitric acid of 1·3298
specific gravity added in small portions. The heating by direct steam
is continued until red vapours are no longer evolved from the liquid,
which is a sign that the oxidation is finished.
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