The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Although the use of direct steam is very convenient for heating, since
wooden vessels can be used and the heating quickly accomplished, it
may be dispensed with, and the solutions heated in pans or even not at
all. In this case the oxidation lasts considerably longer than when the
liquid is heated. In the process recommended by Gentele 109 parts of
yellow prussiate are used to 20 parts of green vitriol, each dissolved
in much water. The precipitate is heated for a short time with 51 parts
of nitric acid of 1·2285 specific gravity and 16 parts of sulphuric
acid. The mixture is allowed to stand for several days to complete the
oxidation before the precipitate is separated from the liquid.
In Hochstätter’s method, solutions of 6 parts of yellow prussiate in
15 parts of water and of 6 parts of green vitriol in 5 parts of water
are mixed. To the precipitate 24 parts of strong hydrochloric acid and
1 part of sulphuric acid are added, and then a solution of bleaching
powder in 80 parts of water until the liquid smells distinctly of
chlorine. Apart from the fact that this method does not employ
equivalent quantities of iron salt and yellow prussiate, it is also
to be regarded as unsuitable, since the addition of sulphuric acid
produces calcium sulphate, which, being soluble with great difficulty,
will be precipitated along with the blue, making the shade lighter. The
addition of sulphuric acid should be omitted and only hydrochloric acid
used, the calcium chloride formed by the decomposition of the bleaching
powder being very soluble in water. Many formulæ given for the
manufacture of Chinese blue are said to produce a pigment of special
beauty. This, however, is incorrect. Chinese blue is a compound of
fixed composition, which is always formed when equivalent quantities of
the salts are used and the precipitate converted into the blue compound
by one of the oxidising agents given. It is most simple to use nitric
acid as the oxidising agent; for this purpose the presence of chlorine
in the acid is harmless. When sufficient space and time are allowed, a
special oxidising agent may be omitted and the oxidation of the white
precipitate accomplished by atmospheric air.
In working in this manner the precipitate is washed several times
with water, and spread in a thin layer upon boards which are placed
in rows one above the other. In a short time the mass turns blue on
the surface, but the pale colour remains underneath much longer, since
the access of oxygen to the interior is difficult. The boards must be
left until the mass has a uniform colour throughout. In order that the
paste shall not dry too thoroughly whilst on the boards it is desirable
to make it very fluid. If the precipitate has been completely washed
before the oxidation the product is finished after drying, but if a
portion when completely dried shows a crystalline incrustation, salts
are still present, which must be removed by careful washing.
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