The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Attempts to make ultramarine artificially would naturally be based on
the analysis of the natural product. The following comparison of the
compositions of natural and artificial ultramarines shows how nearly
the artificial product approaches the natural:—
NATURAL ULTRAMARINE.
Clément and Desormes. Gmelin.
Silica 35·8 per cent. 47·31 per cent.
Alumina 34·8 ” 22·00 ”
Soda 23·2 ” 12·06 ”
Lime 3·1 ” 1·55 ”
Sulphuric acid —— ” 4·68 ”
Sulphur 3·1 ” 0·19 ”
Water and organic matter —— ” 12·21 ”
ARTIFICIAL ULTRAMARINE.
+------------------------------------------------------------------+
| | Blue. | Green. |
+-------------+------------+------+--------+-----+-----------------+
| Observer. |Warrentrapp.|Elfen.|Brunner.|Pohl.| Gentele. |
| | | | | | |
| Silica | 45·60 | 40·0 | 32·54 |36·67|} 47·31 |
| Alumina | 23·31 | 29·5 | 25·25 |32·12|} |
| Soda | 21·47 | 23·0 | 16·91 |21·45| 39·93 |
| | | | | |(sodium silicate)|
| Potash | 1·75 | —— | —— | —— | 3·92 |
| Lime | 0·02 | —— | 2·38 | —— | 1·13 |
| Sulphuric | | | | | |
| Acid | 3·83 | 3·4 | —— | 2·08| —— |
| Sulphur | 1·69 | 4·1 | 11·63 | 7·22| 6·62 |
| Iron | 1·06 | 1·0 | 2·25 |trace| 1·95 |
| | | | | |(ferric silicate)|
| Water | —— | —— | —— | —— | —— |
| Oxygen | —— | —— | 9·04 | 0·58| —— |
+-------------+------------+------+--------+-----+-----------------+
I. Szilasi found three samples of green ultramarine to have the
following composition:—
Water 2·20 1·20 1·19
Aluminous residue 1·80 1·42 1·41
Silica 16·73 17·18 16·74
Aluminium 15·92 15·87 16·15
Sodium 18·42 18·18 18·10
Sulphur 7·19 6·97 6·85
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