The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
There are many other analyses in addition to those we have given and
agreeing with them, so that there is no doubt as to the composition of
ultramarine, but as to the manner in which the elements are grouped
nothing is definitely known. Some chemists are of the opinion that
the colouring principle of ultramarine is a sulphur compound of iron,
whilst others oppose this view and consider that the colour is due
to the combination of a double silicate of alumina and soda with an
unknown sulphide of sodium. Although no blue or green compound is
known of corresponding composition, the majority of chemists incline
to the latter view. Experience has shown that the presence of iron in
any of the materials used in the manufacture of artificial ultramarine
is very dangerous to the success of the operation, and at the least
considerably injures the beauty of the product.
Although the manufacture of ultramarine is now very well known, it
cannot be denied that some works produce a pigment of a shade which
cannot be obtained by others. These works keep their method very
secret, so that it is not possible to say with certainty whether they
have introduced a process varying from that commonly known, or whether,
by carefully watching the process, they have achieved great technical
dexterity in the manufacture of this product. The latter appears the
most probable, for in order to obtain a good result, many experiments,
and an accurate knowledge of the raw materials, are necessary.
The raw materials used are as follows: pure aluminium silicate, sodium
sulphate, soda, sulphur, coal. The aluminium silicate is used in the
form of fine china clay or kaolin, sodium sulphate and soda must be
used in the anhydrous form, the sulphur is the ordinary commercial
substance purified by distillation. Charcoal or coal containing little
ash can be used.
Whilst the remaining raw materials are always of similar composition,
the china clay from different localities possesses a very varying
composition. This substance must be carefully chosen. There is hardly
any kaolin which is naturally of sufficient purity to be used without
purification; it is well known that the china clay used for porcelain
is subjected to a thorough preparation before it is used. Kaolin, like
all clays, has been produced by the decomposition of feldspar; when
the aluminium silicate so formed was able to deposit without foreign
admixtures, that mineral was formed which is the purest of all clays
and is called kaolin. The more foreign substances are mixed with
the aluminium silicate the further is the clay removed from kaolin.
The impurities which generally accompany the aluminium silicate are
quartz sand, chalk and ferric oxide. We distinguish accordingly
between kaolin, white clay or pipe clay, clay, and lastly marl, a clay
containing much chalk.
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