The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
It has been already remarked that there is no agreement as to the
composition of the colouring principle of ultramarine; some maintain
that it is an iron compound, whilst others regard the iron found in
ultramarine as an accidental impurity, which has no connection with
the colour. Recently this point appears to have been decided from the
results of many most accurate analyses of ultramarine. It has been
found that its chemical composition shows the greatest similarity with
the mineral nepheline.
Nepheline is a double silicate, its composition is expressed by the
following formula: Na₂O.SiO₂ + Al₂O₃.2SiO₂. By a comparison of the
analyses of green and blue ultramarine with that of nepheline, it is
seen that blue ultramarine may be regarded as nepheline combined with
sodium pentasulphide, whilst green ultramarine is nepheline combined
with sodium bisulphide. If this is the correct view, the two species of
ultramarine have the following formulæ:—
2{Na₂O.SiO₂ + Al₂O₃.2SiO₂} + Na₂S₅.
2{Na₂O.SiO₂ + Al₂O₃.2SiO₂} + Na₂S₂.
Ultramarine is one of the most permanent pigments. It is not altered by
the substances with which a pigment generally comes in contact. Being
a sulphur compound, it retains its colour completely in air containing
sulphuretted hydrogen. By acids, even weak organic acids such as malic,
citric or tartaric, it is rapidly decomposed, sulphuretted hydrogen
being evolved, and a greyish white residue left. It is sometimes found
that the sugar used in making lemonade produces a perceptible smell of
sulphuretted hydrogen. This is due to ultramarine, which has been added
to the sugar to hide its yellow colour.
From the preceding account of the manufacture of ultramarine it will be
understood that there exist only two species of ultramarine, green and
blue. In commerce a large number of different shades are found, which
are not to be regarded as pure ultramarine; they owe their particular
shade to additions. By mixing in a white pigment, such as barytes or
starch, the paler shades are obtained; by adding a small quantity of a
pure red pigment a colour with a violet tinge is produced. In a similar
manner any number of shades of ultramarine can be obtained.
The following account is taken from a new comprehensive work by J.
Wunder, on the different ultramarines.
Public-domain text, read in full here on John Shaqi.
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