The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The muffles used for finishing the ultramarine are similar to those
used in making green ultramarine; they are generally 50 centimetres
wide and 100 to 120 centimetres long. A muffle of this size will
contain 6 to 18 kilogrammes of green ultramarine. The temperature is
gradually raised to a gentle red heat, each muffle being provided in
front with an iron plate which prevents the cooling of the contents by
the external air. When the charge in the muffles is carefully observed,
it is noticed that the blue colour first appears at the surface and
the edges, _i.e._, at those places where the oxygen of the air has
unrestricted access. The mass is frequently turned over with an iron
rake, in order to expose all parts to the action of the air; samples
are frequently taken in order to observe the moment at which the
colour has reached its greatest intensity, when the heating is at once
stopped. By proper treatment about half an hour is required to convert
the charge of a muffle of the above dimensions into ultramarine of the
deepest blue. The hot mass is drawn out of the muffles and spread out
upon flags so that it may cool quickly. During the cooling the colour
is often observed to become considerably darker, which is a sign that
the ultramarine has not been heated for a sufficient length of time.
Mechanical arrangements are often used to continually turn over the
ultramarine in the muffles, which are then made in the form of
cylinders in which the ultramarine is continually turned by a stirrer
provided with wings. The whole arrangement is very similar to the
apparatus used for roasting coffee.
The ultramarine is then carefully ground to a very fine meal; it is
tolerably hard, and granite stones should be used, ordinary stones
would be too quickly worn down. It is not possible, by the most careful
grinding, to convert ultramarine into that condition of fine division
which is necessary if it is to be ground into paint; grinding must be
followed by levigation. The various qualities and shades brought into
the market differ only in regard to the fineness of their particles;
they do not vary in chemical nature, for the substance has always the
same composition.
It occasionally happens in ultramarine works that a charge does not
turn out a bright blue; the product is then sold as inferior quality
at a lower price, or is mixed with a larger quantity of good material.
In working by a settled process the different shades of ultramarine
vary in composition between narrow limits; the difference is caused by
variations in the raw materials.
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