The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
=Chlorine and Steam Process.=—Chlorine does not attack iron at 150° to
250° C. The reaction is carried out in heated iron boxes 1 metre wide,
2 metres long and 65 centimetres high. The blue is spread out in a
layer 2 centimetres thick on earthenware plates, which stand one above
another at a distance of 5 centimetres, each supported on three feet.
The plates are introduced by means of iron tongs through large openings
in the top of the box; after filling iron plates are screwed on to the
openings, through them pass sheet-iron tubes reaching to the bottom,
in which thermometers can be lowered on wires. The iron boxes stand in
heated chambers, which have openings corresponding with the openings
in the boxes, and shut off from the interior of the furnace. Chlorine
and steam are led into the iron boxes at both ends through lead tubes
reaching to the bottom; the parts of these tubes in the furnace and the
iron boxes are protected by wide sheet-iron tubes, the space between
being filled with clay. The gases evolved, hydrochloric acid, sulphur
chloride and steam, pass from the covers through earthenware pipes into
boxes filled with limestone, upon which water drops, and thence to
the chimney. After filling, the boxes are heated to 280° C. and steam
introduced to remove sulphur; they are then allowed to cool to 160° C.,
when chlorine and steam are led in for three hours. The violet is then
finished, and the residual gases are blown out by a fan.
=Hydrochloric Acid and Air Process.=—The operation is conducted in
the same iron boxes, upon the bottoms of which, beneath the openings,
are earthenware dishes into which hydrochloric acid can be poured
through earthenware pipes. The chimney draught must be strong enough
to draw sufficient air through these pipes into the boxes. After the
temperature has been maintained for seven hours at 220° to 230° C.,
hydrochloric acid being poured in from time to time, the blue is
changed to a dull violet, which becomes brighter when hydrochloric acid
is repeatedly added at diminishing temperatures, 210°, 200°, 180° and
160° C. More recently the iron boxes have been replaced by stone chests
or by chambers above the ultramarine furnaces, the temperature in this
case being kept at about 200° C.
=Ammonium Chloride Process.=—A mixture of ultramarine blue with 5 per
cent. of ammonium chloride is heated during fourteen days in porous
crucibles placed in the upper chambers of the ultramarine furnaces,
when the contents of the crucibles become a handsome violet throughout.
If sodium nitrate is used together with ammonium chloride, the violet
is formed in a much shorter time. After washing, the violet still
contains nitrogen; on ignition or heating with strong alkalis it
loses ammonia. Unfortunately, this fine violet is decomposed by the
continued action of moist slaked lime. The violets made by the first
two processes absorb ammonia when this gas is led over them at 180° to
200° C., and it cannot be removed by washing.
Public-domain text, read in full here on John Shaqi.
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