The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
=Copper Arsenite.=—The compounds of arsenious acid with copper are
among the most handsome and bright colours which exist. It is thus
to be regretted that these pigments are disappearing more and more,
and indeed with every reason, from the pigments permitted by law.
In the end they must fall into complete disuse. It is a matter of
common report that these pigments, and particularly emerald green,
have frequently caused arsenical poisoning. Numbers of people have
been repeatedly made ill by the dust of emerald green fixed on light
fabrics, such as are used for ball dresses, simply by albumin or
dextrine, and brought into the air by the movements of the dancers.
It has been further shown that the air of rooms papered with hangings
coloured by emerald green contains small quantities of the most
poisonous of all arsenic compounds, arseniuretted hydrogen.
Although it is in the interest of colour makers to produce the
brightest possible colours, yet, on account of their dangerous
properties, pigments containing arsenic should be quite excluded.
In several countries their use is forbidden by law. Since there are
several pigments which can compete in brightness with the arsenic
colours, it is to be hoped that the latter will shortly disappear from
commerce.
=Scheele’s Green, Swedish Green.=—A solution of 32 parts of potash is
boiled with 11 parts of white arsenic (arsenious acid) until the latter
is completely dissolved. This solution of potassium arsenite is mixed
with a hot solution of 32 parts of copper sulphate free from iron. The
beautiful green precipitate is washed with hot water and dried. These
directions for the preparation of copper arsenite are due to Scheele,
the discoverer of the pigment. It can be prepared by several other
methods.
When white arsenic and copper sulphate are dissolved together, and
caustic soda added to the boiling solution, Scheele’s green is
precipitated. When made by this method the pigment must be very
carefully washed; if the excess of caustic soda is not completely
removed it is very hard when dry, and is difficult to powder. In order
to obtain darker greens the quantity of copper sulphate is increased.
A particularly bright green is obtained by dissolving copper sulphate
in water, with the addition of 12 to 15 per cent. of white arsenic, and
precipitating by a solution of potassium zincate, which is obtained
by boiling caustic potash solution with zinc filings, hydrogen being
evolved.
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