The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The shade of Scheele’s green depends on the relative quantities of
arsenious acid and copper sulphate employed. If the arsenious acid
predominates, a pale product is obtained; when excess of copper
sulphate is used, the colour is pure green. The pigment made according
to the foregoing directions possesses only small covering power. A
product better in this respect is obtained by precipitating a solution
of 100 parts of copper sulphate by a solution of 90 parts of potassium
carbonate, in which 66 parts of arsenious acid have been dissolved.
Scheele’s green is a bright green pigment, which resists the action
of the atmosphere tolerably well. It is easily decomposed by dilute
acids; when strongly heated arsenious acid is set free, and copper
arsenate and arsenide are produced. Copper arsenite is the essential
constituent of the pigments sold under the name of mineral green, which
is generally a mixture of copper arsenite with varying quantities of
mountain green.
=Brunswick Green, Green Verditer=, is a mixture of copper arsenite,
copper hydroxide and gypsum. It is prepared by dissolving 100 parts
of copper sulphate in water, adding a solution of ¼ part of arsenious
acid and 10 parts of anhydrous potassium carbonate, and finally
precipitating with milk of lime made from 20 parts of quicklime. The
pale to bluish-green precipitate is washed and pressed into flat cakes,
which are brought into the market and used as lime colours. This
pigment is not adapted for use in oil; when applied in that medium it
darkens considerably.
=Neuwied Green= is made in almost exactly the same manner as Brunswick
green, the chief difference being that a larger quantity of arsenic
is used, and thus a product obtained inclining more to green than to
blue. As a rule 2 to 2½ parts of arsenious acid are used to 100 parts
of copper sulphate. The colours found in commerce under this name very
often consist of mixtures of emerald green and finely ground barytes.
=Copper Oxychloride= was at one time largely used. At present it is
scarcely employed; it has been replaced by handsomer and cheaper
pigments. Copper oxychloride is made by exposing a wet mixture of
copper, copper sulphate and common salt to the action of the air.
To 111 parts of copper sulphate 112·5 parts of copper and the same
quantity of common salt are employed. The mixture is made into heaps,
which are wetted and from time to time shovelled about, so that the
air may come in contact with all portions of the mass, and the copper
chloride be converted into basic chloride. It is advisable to allow the
heaps to dry frequently after they have been turned over, so that the
air may more readily penetrate into the interior. Copper oxychloride
has a pale green colour of little brilliance. On this account it is
hardly ever used now; it forms the raw material for the preparation of
Bremen green.
CHAPTER XXIX.
EMERALD GREEN.
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