The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The grape residues are effective on account of the sugar, which is
transformed into alcohol and then into acetic acid. Residues which
have been extracted with water after pressing should not be used in
the manufacture of verdigris; they contain but little sugar and hence
undergo a very feeble acetic fermentation. When such residues are used
the verdigris is often accompanied by black spots of copper sulphide
upon the plates; this is due to incipient decomposition of the residues.
As a practical test for the termination of the process a strip of
copper is plunged into the heap and left for some hours. It should
be covered by a uniform coating of verdigris; if it is covered with
small drops that is a sign that the process is not completed and the
heaps must be left some time longer. The course of the process can be
simply and safely followed by means of a thermometer. This is placed in
a perforated copper tube and plunged into the interior of the heap. A
continuous rise of temperature indicates a steady increase of chemical
action; the temperature of the room is regulated in accordance. When
the temperature in the interior of the mass begins to fall the process
is nearing the end. More heat is now supplied to assist the chemical
action. The process is at an end when, in spite of external heat, the
temperature of the heap decreases and approaches the temperature of the
air of the room.
Verdigris can also be made by placing sheet copper and grape residues
in layers in pots, which are deposited in a room of fairly uniform
temperature, such as a cellar. This method has the advantage that the
formation of the verdigris is finished in a shorter time, which is more
than counterbalanced by the labour and expense of filling the pots.
The copper plates, when removed from the heaps or pots, are covered by
a crust of thin needle-shaped crystals of a bright green colour. They
are shaken to free them from the adhering grape skins and seeds, and
then treated with weak vinegar, in which they are dipped; they are then
left standing on edge for several days. This treatment with vinegar has
the object of converting the neutral salt formed on the plates into
basic salt. The dipping into vinegar and exposure to air are repeated
six to eight times, when the originally pure green crust on the plates
is gradually changed into bluish-green verdigris. These processes
are continued until the plates are covered uniformly by a layer of
verdigris about 5 centimetres thick. The crust is then scraped off by
copper knives and stirred with water to a paste, which is pressed in
leather bags in rectangular moulds. The lumps are then slowly dried in
the air.
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