The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Plates which have been once used give a larger quantity of verdigris
in a second operation, which is to be ascribed to the fact that they
possess a larger surface than unused plates. New plates are made more
susceptible to the further action of the acid by dipping in strong
vinegar, by which they become covered with a layer of copper acetate.
The verdigris obtained by this method consists of crystalline scales of
a pale bluish-green colour, which produce a pale blue powder. In crude
verdigris grape seeds are often found, and occasionally stalks and
pieces of metallic copper. These admixtures are a consequence of the
method of manufacture and cannot be regarded as adulterants. Gypsum is
to be regarded as an adulterant. Verdigris often contains basic copper
carbonate.
Verdigris behaves in a peculiar manner with water. In contact
with a small quantity it swells to a bluish-green mass, which
becomes quite warm. Neutral copper acetate and the basic salts
2Cu(C₂H₃O₂)₂.Cu(OH)₂.5H₂O and Cu(C₂H₃O₂)₂.2CuO.1½H₂O are formed, the
latter of which is insoluble.
By the addition of a larger quantity of water the basic compounds are
decomposed, neutral copper acetate dissolves, and a mixture remains
of the compound Cu(C₂H₃O₂)₂.2CuO.1½H₂O and a brown basic acetate
containing still less acetic acid. On account of this peculiar
behaviour of verdigris towards water some care is required when it is
used as a water colour. A very dilute solution is not green, but has an
indefinite shade.
=Distilled or Crystallised Verdigris= consists of neutral copper
acetate, Cu(C₂H₃O₂)₂.H₂O. It can be made from blue verdigris by
treating with the amount of acetic acid required to completely
neutralise the copper oxide, or by decomposing copper sulphate with
the acetate of a metal which forms an insoluble or difficultly soluble
sulphate.
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