The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Crystallised verdigris is very simply made from ordinary verdigris;
the latter, whilst still moist, but containing only a small quantity
of water, or the acetic acid would be too largely diluted, is brought
into a pan and strong acetic acid poured over. Strong pyroligneous acid
may be used, its empyreumatic odour is without influence on the quality
of the product. The pan is heated until the contents almost, but not
quite, boil. They are frequently stirred so that the particles at the
bottom are brought in contact with the acid. A dark green solution is
formed; when its colour no longer increases in depth it is allowed to
stand until suspended solids sink to the bottom. The clear solution is
then drawn off and rapidly evaporated in shallow copper pans. It is
important that the liquid should not contain an appreciable quantity
of free acid. When a crystalline skin begins to form on the surface of
the solution it is drawn off into the crystallising vessels. These are
made of glazed earthenware; wooden rods are placed in them, on which
the crystallisation takes place. In order that large crystals shall
be obtained, it is necessary to maintain a regular temperature in the
room in which the crystallising vessels are placed. It is heated at the
commencement, and the temperature is allowed to sink a little towards
the end of the operation. From twelve to fourteen days are required to
obtain large crystals. The mass of verdigris crystals adhering to each
rod weighs 2·5 to 3 kilogrammes. The residual liquid is a saturated
solution of verdigris, and is used in the next operation. It is only
necessary to heat it with the residue from the first operation and some
acetic acid in order to obtain a crystallisable solution of verdigris.
The residue in the pan contains metallic copper, grape stems and
seeds, and basic copper acetate. The copper is extracted by moistening
with acetic acid and exposing to the air, when verdigris is formed,
which is added to a later batch.
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