The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
When only hard waters containing much lime are at the service of the
manufacturer, turbid solutions are often obtained, which must be
filtered before use. In many cases this can be avoided by adding milk
of lime to the water in a large vessel; the free carbonic acid unites
with the lime, and thus the carbonate of lime, which is only soluble in
water containing free carbonic acid, separates as a fine precipitate.
Water which has been treated in this way becomes clear after some time,
through the deposition of the carbonate of lime; it is then soft water.
In order to separate the carbonate of lime in this way, no more than
the requisite quantity of milk of lime should be added, so that no lime
remains in excess, since this would cause precipitates when salts of
lead, copper, iron, etc., were dissolved. In many cases—for example,
when lead or barium salts are dissolved—the lime contained in the water
can be made harmless by slightly acidifying with acetic or nitric acid.
Water which contains sulphate of lime (gypsum) is equally useless for
many purposes, as, for example, the solution of lead and barium salts.
These metals form insoluble compounds with the sulphuric acid, which
render the solution turbid, and can be removed only with difficulty by
filtering, on account of their great fineness. They are more easily
removed by allowing to settle.
Water containing gypsum often contains in addition small quantities of
sulphuretted hydrogen. However small the quantities of this gas may
be, they still make the water absolutely useless for certain purposes
in the manufacture of colours; for example, for the preparation of
all pigments containing lead which are obtained by precipitation. The
sulphuretted hydrogen forms black compounds with lead, copper, bismuth,
mercury and other metals, which impair the brilliance of the colour. A
colour made under these conditions is never clean, its hue is injured
by the admixture of the black substance.
Water which contains much common salt (sodium chloride) is unsuitable
for the solution of lead, mercury and silver salts. In consequence of
the great affinity of these metals for chlorine, turbid solutions are
obtained when their salts are dissolved in water containing common salt.
Some waters contain a considerable quantity of iron. Such waters
deposit on evaporation, and often on standing exposed to the air, a
brown powder of ferric hydrate, which would have considerable influence
on the shade of a pigment. White pigments, in the preparation of which
such a water is used, have always a brownish tinge; yellow and red
pigments are also unfavourably affected.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account