The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The dried lees are carbonised in iron tubes, protected from the
fire by a thin coating of clay mixed with chopped hair so that the
coat more readily adheres to the iron. Old stove pipes or cast-iron
gas or water pipes may be used. The tubes are about one metre long;
they are closed with well-fitting covers, in one of which is a small
opening through which the gases produced on heating can escape. These
covers are fastened on air-tight with clay. The process begins by
affixing the unperforated lid, and packing with a wooden rammer the
dry lees as tightly as possible into the tube; the second lid is then
luted in place. The tubes are placed near one another in a suitable
furnace and first slowly heated at the back, _i.e._, the end closed
by the unperforated cover. At the commencement of the operation heat
must be gradually applied. With too large a fire the products of
dry distillation might be evolved in sufficient quantity to force
the covers from the tube; air would then enter and the contents be
burnt. When the hinder part of the tube is red-hot, the heating is
conducted forward, and finally the whole length of the tube is brought
to a good red heat. The termination of the operation is shown by the
disappearance of the pointed flame of the products of distillation
which protrudes from the opening in the cover of the tube. When this
occurs, the fires are drawn; the tubes are left to cool in the furnace
until they can be taken out by the hands protected by wet cloths. The
covers are at once taken off and the hot contents emptied into a large
tub filled with water, which is thus soon raised almost to boiling
point. The time required for washing is thus considerably shortened.
The charcoal falls from the tubes in lumps, which soon fall to a fine
powder in the water. Wine lees consist of a mixture of yeast cells and
small crystals of tartar (a mixture of the tartrates of potassium and
calcium). On ignition these salts are converted into carbonates, by
which the particles of carbon are united. Potassium carbonate is very
readily soluble in water; in contact with the warm water it dissolves
in a very short time, the carbon particles then fall apart.
When the charcoal has settled to the bottom of the vessel the liquid
is drawn off. It can be utilised in a colour works, since it is a
fairly strong solution of potassium carbonate. The charcoal is mixed
with calcium carbonate, arising from the decomposition of the calcium
tartrate, and with the other insoluble salts which yeast ashes contain
in some quantity. These salts would prevent the proper grinding of the
charcoal; they are therefore removed by treatment with hydrochloric
acid after the water has been drawn off as completely as possible.
A small quantity of hydrochloric acid, diluted with an equal volume
of water, is poured over the charcoal, an effervescence of carbonic
acid follows, the easily soluble calcium chloride is formed and the
remaining salts are also dissolved.
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