The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
An accurate analysis of a water is much too complicated for the
manufacturer; it is sufficient for him to convince himself of the
absence of certain substances. Water which, some time after the
addition of a little tannic acid solution, acquires a clear green or a
bluish to black shade contains much iron, and is useless. Water which
coagulates a large quantity of a solution of soap in alcohol is very
rich in carbonate or sulphate of lime. In order to decide approximately
in what relative proportion these salts are present, a solution of
barium chloride is added to the water so long as a precipitate forms.
If this disappears completely on the addition of nitric acid, the
water contains only carbonate of lime; if it only partly dissolves,
sulphate of lime is also present. The presence of chlorine is shown
by a considerable turbidity on acidifying the water with nitric acid,
boiling and adding silver nitrate. If the precipitate obtained on the
addition of a lead salt is not pure white, but discoloured, the water
contains sulphuretted hydrogen, which has formed black lead sulphide.
In order to test the water for organic substances, about a litre is
evaporated to dryness in a porcelain dish, and the residue heated to
redness; if it turns brown and black, and possibly gives off a smell of
burnt feathers, the water contains much organic matter.
Pure water is coloured permanently red by a solution of potassium
permanganate; but if it contains organic matter, the solution is
decolourised after some time and a brown precipitate is deposited at
the bottom. From the amount of this precipitate an idea of the quantity
of organic matter present may be obtained.
It is only necessary to be very scrupulous concerning the quality
of the water when it is to be used for the solution of salts or the
extraction of dye-woods. For washing precipitates, which requires a
large volume of water, there can generally be used, without detriment,
water containing much lime, but it must be free from iron and
sulphuretted hydrogen. The latter is particularly harmful to most of
the lead colours, which would lose in beauty by washing with water
containing this substance.
It is hardly necessary to say that the water used in colour making must
be quite clear. Muddy river water must in every case be completely
freed from the solid particles contained in it, either by settling or
by filtering. Filters filled with well washed sand give good results
for this purpose.
=Chlorine=, Cl = 35·5.—For some operations in colour making it is
necessary to employ chlorine. This is a greenish yellow gas at
ordinary temperatures, which is characterised by a suffocating smell
and the energy with which it unites with most elements. On account of
its injurious effects on man certain precautions have to be observed
in preparing chlorine, and it is advisable to erect the apparatus
necessary for its production in a separate room, so that the workmen
are not injured by the gas.
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