The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
=Yellow Enamels= are coloured by silver, antimony oxide combined with
litharge, or ferric oxide; from the latter a red can also be obtained.
To produce a yellow enamel by means of silver the article is first
enamelled white at a low temperature; silver oxide is then applied
where required, and the article again heated. It then frequently
happens that the surface has a metallic appearance owing to the
reduction of a part of the silver oxide to metallic silver. When this
coating is scraped off the enamel beneath is found to be coloured a
fine yellow.
The antimony yellow is obtained by mixing 1 part of antimony oxide, 1
part of alum and 1 to 3 parts of white lead, according to the depth of
colour required. These finely-powdered materials are intimately mixed
with 1 part of sal ammoniac, and heated in an open vessel with stirring
until the yellow colour appears. The vapours of the ammonium chloride
indicate the proper temperature for the operation. When this substance
is completely volatilised the temperature should not be further raised,
or the mixture would fuse.
By means of ferric oxide a fine and durable yellow is produced; the
quantity employed must not be too large, or a red colour will result. A
very high temperature is required for burning in this colour. The alum
used in making the yellow enamel colours serves to prevent the oxides
from fusing.
=Red Enamel.=—Ferric oxide is generally used. When a purple red is
required it is obtained either directly from metallic gold or from
purple of Cassius.
Red iron enamel is made by slowly heating 20 to 25 parts of pure
ferrous sulphate with 10 parts of aluminium sulphate until all the
water of crystallisation is expelled, when the temperature is gradually
raised to an intense heat. The shade depends upon the temperature: the
higher it is the darker is the colour. Tests are taken from time to
time of the mixture, and rapidly cooled. Hot ferric oxide is black,
consequently the shade can only be judged with complete certainty in a
cooled portion. Although the temperature required for the preparation
of this colour is very high, yet it ought not to rise so far that the
magnetic oxide is produced, a small quantity of which would cause the
enamel to appear dirty red, since it gives to the flux a blackish
green colour. The red ferric oxide colour should not be dissolved in
the glass of the enamel, but should be embedded in it. Thus, when the
enamel is burnt on, the temperature should not rise so high that ferric
silicate is formed, otherwise a yellow or even completely black enamel
results.
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