The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The manufacture of leaf metal and bronze powder is frequently conducted
in the same works, which also often prepare the requisite alloys; we,
therefore, give a few examples of the composition of the alloys which
produce certain shades. The more zinc the alloys contain the lower is
their melting point, the greater their brittleness and hardness and
the paler their colour. An increase in the copper causes the colour
of the alloy to approach more nearly to that of gold, and increases
the malleability, a property useful in making leaf metal, but not
desirable in making metallic powder. A zinc copper alloy which contains
between 1 and 7 per cent. of zinc has an almost pure red, or even a
dark red colour; an alloy containing 7·4 to 13·8 per cent. of zinc has
a pure golden yellow colour, between 16·6 and 25 per cent. of zinc a
yellow appears. An increase of the percentage of zinc above this point
produces the colour of brass; it is noteworthy that an alloy containing
still more zinc, 33 to 41 per cent., again shows a reddish colour,
which is most developed when the alloy contains equal parts of zinc and
copper. If the zinc is increased still further the shade gradually goes
over to white; this change is already observed in an alloy containing
51 per cent. of zinc, which shows a pure golden yellow colour, and is
very brittle. When the zinc rises to 53 per cent. the colour is reddish
white; at 56 per cent. it is yellowish white, at 64 per cent. bluish
white, and between 75 and 90 per cent. the alloy is bluish-grey.
The alloys for bronze powders of different shades have the following
composition, according to R. Wagner:—
Copper, Zinc
per cent. per cent.
Pale yellow 83 17
Red 94-90 6-10
Deep red 100
Bronzes from English, French and Bavarian works contain the following
percentages of copper:—
ENGLISH BRONZES.
Orange 9·82 per cent.
Deep yellow 82·37 ”
Pale yellow 80·42 ”
FRENCH BRONZES.
Copper red 97·32 per cent.
Orange 94·44 ”
Pale yellow 81·29 ”
BAVARIAN BRONZES.
Copper red 98·92 per cent.
Violet 98·82 ”
Orange 95·30 ”
Straw yellow 81·55 ”
Speiss yellow 82·34 ”
In each case the remainder of the alloy consists entirely of zinc.
Alloys containing from 1 to 35 per cent. of zinc are only malleable
in the cold. The malleability is at the greatest with a content of
zinc between 15 and 20 per cent.; such alloys are the most suitable
for making leaf metal. Alloys containing between 36 and 40 per cent.
of zinc may be hammered either cold or hot, whilst the former alloys
become brittle on heating. When the percentage of zinc is still further
increased the malleability decreases. The most brittle alloys contain
60 to 67 per cent. of zinc.
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