The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
_The Hydrometer._—In the above table the percentage content of the
ammonia solution is given according to its specific gravity, that is,
according to the ratio between the weight of any volume of the liquid
and the weight of an equal volume of water. According to scientific
principles, only those hydrometers should be used which are graduated
in specific gravities. In spite of all exertions in this direction,
manufacturers have not yet been induced to use such instruments in
every case. Hydrometers, with quite arbitrary scales, such as those of
Baumé and Twaddell, are frequently found in works. These hydrometers
generally only show that a liquid is of so many degrees on the
particular scale, and the manufacturer in using them is restricted
to the following out of a certain recipe which requires the use of
a liquid of a certain strength which is expressed in degrees Baumé,
etc. He does not learn by this how many per cent. of the particular
substance are dissolved in the water when the liquid has a certain
hydrometric strength.
For the sake of uniformity, it is urgently to be desired that all
manufacturers who use the hydrometer to estimate the content of a
liquid in ammonia, potash, soda, hydrochloric, sulphuric, nitric acids,
etc., should employ simple specific gravities. This is desirable,
because the percentage strength of a solution, corresponding to the
specific gravity, can be at once accurately found from tables. On
these grounds, in the present work, we have restricted ourselves to
tables showing simply the specific gravities of solutions and the
corresponding composition.
=Sal Ammoniac or Ammonium Chloride=, NH₄Cl = 53·5.—This substance comes
into commerce in the form of a white crystalline meal, more rarely in
the form of sugar loaves (crystallised sal ammoniac) or of flat cakes
(sublimed sal ammoniac). It is usually very pure, since impure forms,
generally containing much iron, are difficult of sale. At a particular
temperature sal ammoniac is volatile; it is used in certain mixtures
in order to prevent the temperature, on heating, from rising beyond a
certain point. Like ammonia, it is more used in dyeing.
=Ammonium Sulphide=, NH₄HS.—This compound is obtained by leading
sulphuretted hydrogen into ammonia solution so long as it is dissolved,
and a test portion of the liquid still gives a white precipitate with
a solution of magnesium sulphate. Ammonium sulphide decomposes by long
standing in the air, sulphur being separated. It gives precipitates
with the salts of certain metals, for example, iron, cobalt, manganese,
zinc, nickel. These precipitates, which consist of the sulphides of the
metals, are not formed by sulphuretted hydrogen in acid solutions.
ACIDS.
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