The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The decoction of cochineal is difficult to filter. Paper cannot be
used, because the pores are so rapidly stopped up that new filters
would be continually required. Fine silk is the most serviceable; it
should not be washed with soap—the alkalinity of the small quantity of
soap the fabric would retain would affect the colour. The decoction is
made in a well-tinned copper pan, all other vessels should be of glass
or porcelain, which are most easily cleaned, and great cleanliness
is the prime essential to the success of the process. The greatest
care is required to prevent the contact of the liquid with iron during
the whole process, the smallest trace of this metal would result in a
discoloured product.
The essentials of the manufacture of carmine on the large scale are
that the colouring matter is dissolved in water, and precipitated by
the addition of an aluminium salt, generally alum, absolutely free from
iron. The more slowly the carmine separates the finer is its colour.
It is generally observed that the last portions to precipitate show
the brightest shade. This is because the foreign substances occurring
with the carminic acid in the decoction are thrown down with the first
portions of the precipitate. In the process of Frau Cenette, famous for
the beauty of the product, a solution is made from which the whole of
the carmine is separated in about three weeks. During this long time
the majority of the substances which have been dissolved in the water
together with the carminic acid are decomposed; the liquid acquires an
unpleasant smell, and is covered with mould. In the author’s opinion
so good a product is obtained by this process because the greater part
of the impurities is decomposed: the nearer the product approaches the
pure compound of carminic acid and alumina, the purer and brighter will
be the shade of the carmine.
It is known that light has considerable influence on the beauty of
carmine. During dull winter days it is quite impossible to produce so
fine a product as in summer. Instead of alum a tin solution may be
used to precipitate the colouring matter; the shade of the product is
different to that of alumina carmine.
CENETTE’S METHOD.—1 kilogramme of finely powdered cochineal is boiled
with 75 litres of water for two hours; 90 grammes of saltpetre are
added, the liquid boiled for three minutes, then 120 grammes of salt of
sorrel (acid potassium oxalate) are added and the liquid again boiled
for ten minutes. The liquid is then completely clarified by standing,
drawn off from the residue by a syphon, and brought into shallow glass
dishes which are placed, protected from dust, in a bright light in
a uniformly warm place. During several weeks the carmine separates,
the last portions being always brighter than the first. The addition
of potassium oxalate has the object of assisting the separation of
the carmine, for acid salts separate the carmine from solutions; the
saltpetre may reasonably be omitted.
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