The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The majority of the recipes for carmine, which are frequently sold at a
high price, differ but little from the above; acid potassium tartrate
is used instead of the oxalate, but the latter is to be preferred
because of the slight solubility of the tartrate. It is important
not to use too strong decoctions of cochineal, and to add only small
quantities of alum. The clear liquid is placed in shallow glass dishes.
After a few days the nature of the deposit should be examined: if a
considerable quantity of a red precipitate has formed, the liquid is
poured off into other dishes, in which carmine again separates during
the following days, and usually of a brighter colour than the first.
For example, 125 grammes of cochineal are boiled with 5 litres of water
during fifteen minutes, 30 grammes of very finely powdered alum are
added to the boiling liquid, which is again boiled for a few minutes,
allowed to clarify and cool. The greater part of the carmine is then
obtained in a few hours, but the liquid still separates carmine after
several days.
According to another formula 500 grammes of cochineal are boiled with
30 litres of water, 60 grammes of cream of tartar are added, then
30 grammes of alum, boiling is continued for several minutes, and
the liquid then allowed to cool. Carmine may be obtained in a very
short time by means of tin solution. The process is similar to that
just given. The liquid which would be set aside for the spontaneous
deposition of the carmine is, however, returned to the pan, and a
solution of pure stannous chloride added in drops, so long as the
solution is still clearly red. The carmine separates at the bottom of
the pan; the liquid drawn off, even when it appears almost colourless,
produces a further small quantity of carmine in a few days.
According to J. J. Hess, a brighter carmine is obtained when the fat of
the cochineal is previously extracted by ether or benzene.
Proposals have often been made to deepen the colour of prepared
carmine; this must be done with the greatest care, for it is very easy
to produce a less handsome instead of a finer pigment. The carmine is
moistened with distilled water containing about 5 per cent. of ammonia
solution.
Carmine readily dissolves in ammonia. This property may be applied to
test its purity, pure carmine should dissolve without residue in 5 to
6 times its quantity of ammonia. Any considerable residue denotes an
intentional addition of some adulterant. Starch, vermilion, and cheaper
lakes are used for this purpose. The red solution obtained by treating
carmine with the above quantity of ammonia may be used as a red ink.
This solution can also be used to purify carmine; when it is allowed to
stand in an uncorked bottle for some time the ammonia escapes, and the
greater part of the carmine is deposited as a very fine powder.
Public-domain text, read in full here on John Shaqi.
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