The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
=Sulphuretted Hydrogen=, H₂S = 34.—This is a gas of acid properties
smelling like rotten eggs; it precipitates the sulphur compounds of
many metals when led into the acid solution of the corresponding
salt. This substance is seldom required in colour works, so that it
is convenient to have an apparatus which permits of the preparation
of any required quantity. Fig. 3 represents an apparatus devised by
the author, which is well adapted for the preparation of sulphuretted
hydrogen. It consists of a small, wooden tub, on whose upper edge lies
a thick paper ring, so that the lid may be pressed down air-tight by
the screws B. Through the lid pass a tap-funnel, T, a movable screw,
S, and a tube, R, to carry away the gas. On the screw S hangs a basket,
K, by a handle; this is filled with pieces of iron sulphide as large as
nuts. The tub is filled to about one-third of its height with a mixture
of 9 parts of water and 1 part of sulphuric acid.
[Illustration: FIG. 3.]
When sulphuretted hydrogen is required the basket is lowered by the
screw, S, until it dips in the liquid; according as the basket dips
more or less into the liquid a fast or slow current of the gas is
obtained. When the gas is no longer required the basket is raised out
of the liquid, and the evolution of gas at once ceases. The funnel, T,
serves for the introduction of the liquid, the tap, H, for drawing off
the iron sulphate solution, which can be used with advantage for the
preparation of fine iron colours. The apparatus should not be opened so
long as sulphide of iron remains in the basket.
=Sulphuric Acid= comes into the market in two different forms: oil
acid; both are used in colour making. _Oil of Vitriol_, H₂SO₄ = 98, is
a colourless, oily liquid of high specific gravity; it is generally
tolerably pure, and contains, as a rule, only a small quantity of
lead, the presence of which is indicated by a turbidity on largely
diluting the acid. The amount of pure sulphuric acid in the liquid
is practically determined by taking the specific gravity. The table
indicates the relation between the specific gravity and the content of
sulphuric acid.
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