The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
To obtain hæmateïn in the pure state it is then only necessary to add
sufficient acetic acid to decompose the hæmateïn ammonia compound.
Hæmateïn separates as dark violet crystals, which readily dissolve in
water and alcohol; its aqueous solution gives blue precipitates with
the majority of the metallic salts. This behaviour of hæmatoxylin
towards ammonia explains the increase in colouring power of logwood,
which has been exposed for a long time to the action of the air in the
rasped state. Through the action of the ammonia in the air a larger
quantity of the hæmateïn ammonia compound has been formed. It has
been proposed to facilitate the formation of this ammonia compound
by moistening rasped logwood with a very dilute glue solution and
allowing it to lie in the air. This process can only have the object
of utilising in the formation of hæmateïn the ammonia resulting from
the decomposition of the glue, but in this decomposition deep-seated
reactions occur, which might affect the hæmateïn itself. It thus
appears more suitable to effect the formation of hæmateïn by the direct
use of ammonia. This can be done with little cost by watering heaps of
rasped logwood with ammonia and repeatedly shovelling about the wood
so that it comes into contact with the air. The author has found that
the conversion of hæmatoxylin to hæmateïn is very complete in this
process; care should be taken not to make the layer of rasped wood too
deep, and to take its temperature frequently. In the transformation
of hæmatoxylin to hæmateïn the temperature rises, the rise might be
injurious if it proceeded too far. Thus if the temperature of the
interior of the heap is found to be high the wood should be turned over.
The solution of the logwood colouring matter produces handsome lakes,
all of which have, however, the inconvenient property of acquiring
an ugly grey colour on long standing. The finest and most durable of
the logwood lakes is known as violet lake, which is made with alumina
salts. The best result is obtained when a solution of aluminium
acetate, obtained by precipitating alum with lead acetate, is mixed
with a logwood decoction or a solution of logwood extract. The
precipitate is pale or deep violet according to the amount of aluminium
salt added. After drying to a certain point at a gentle heat it can be
mixed with gum solution to a paste, which is then completely dried.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account