The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
A properly prepared dye-wood extract should dissolve in water without
residue, and the solution when largely diluted should show the
characteristic colour of the wood with no brownish shade, and when the
colouring matter is precipitated from such a solution by a metallic
salt the residual solution should be almost colourless. If the extract
dissolves incompletely in water and the solution is brown after
precipitation of the colouring matter, the extract has been burnt in
the evaporation.
* * * * *
Logwood and logwood extract contain two substances of importance
in dyeing and colour making. These are hæmatoxylin and hæmateïn.
Hæmatoxylin is found in logwood in greatest amount shortly before the
wood is cut. When pure it forms colourless crystals of a peculiar sweet
taste, which are soluble in cold water with difficulty, more easily
in hot, and readily soluble in alcohol or ether. The composition of
hæmatoxylin is expressed by the formula C₁₆H₁₄O₆.
Hæmatoxylin is not a colouring matter. It is important because from it
is obtained the essential colouring matter of logwood—hæmateïn. When a
trace of ammonia is added to the colourless solution of hæmatoxylin,
the liquid at once becomes dark red owing to the formation of hæmateïn.
When a larger quantity of ammonia is added the liquid acquires a deep
red colour, and then contains only hæmateïn (its ammonia compound),
which is formed according to the following equation:—
C₁₆H₁₄O₆ + NH₃ + O = C₁₆H₉O₅.NH₄ + 2H₂O.
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