The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Tschirch gives the following method for obtaining chlorophyll: Green
leaves (grass), not containing tannin, are extracted with boiling
alcohol, the extract cooled, filtered and evaporated until a sticky
mass remains. This is washed with hot water until the washings are
colourless, and the residue extracted with cold alcohol. The solution
is evaporated to half its volume, the separated crystals are dissolved
in alcohol, and the solution heated on the water bath with zinc dust.
A deep emerald green solution with a red fluorescence is obtained; it
can be preserved unaltered for a long time in blue glass bottles. It
retains its colour in diffused daylight also for a lengthy period. A
beautiful green chlorophyll lake is obtained by boiling this solution
with the solution of an aluminium salt and precipitating with soda.
Unfortunately, the lake is not fast. The chlorophyll solution obtained
by this process is quite innocuous, and is well adapted for colouring
liqueurs and confectionery.
=Sap Green.=—This lake, also known as bladder green, is obtained from
unripe yellow (Persian) berries. It can be used as a water colour, but
not in oil painting. This pigment differs from the ordinary yellow
berry lake in colour and chemical composition; the yellow lake is a
compound of xanthorhamnin with the metallic oxide, whilst sap green
contains an uncrystallisable bitter substance, rhamnocathartin.
The lake is obtained from yellow berries which are not quite ripe.
They are broken up and left in a warm place. The mass soon ferments;
after about ten days it is pressed. Four parts of the liquid are then
mixed with 0·5 part of alum and 0·5 part of potassium carbonate. The
salts are dissolved in boiling water, and the solutions added to the
hot sap. The mixture is then evaporated to the consistency of a thick
syrup, which is generally packed in animal bladders, hence the name of
”bladder green”. Some care is necessary in the evaporation to prevent
the burning of the soft mass on the bottom of the vessel. If the
evaporation is carried somewhat further the mass solidifies on cooling;
it is then black, and only transmits green light at the edges. The use
of potash in preparing sap green is attended with the disadvantage that
the hygroscopic nature of the salt prevents the colour from drying. If
magnesia is used instead of potash the lake dries far more rapidly,
but has much less covering power. Sap green is principally used for
colouring paper and leather.
Orange-coloured lakes also can be obtained from yellow berries by
precipitating the decoction with stannic chloride. These lakes are not
directly employed, but are produced immediately upon the fabric in
dyeing.
Public-domain text, read in full here on John Shaqi.
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