The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
=Chinese Green, Lokao.=—Under this description a green lake has
recently been imported from China. It is a valuable pigment. Chinese
green is sold in flat cakes, which are blue, with a green or violet
lustre. The powdered lake is pure green and partially soluble in
water; it contains colouring matter, water and inorganic matter
consisting chiefly of clay and lime.
Chinese green is made in China in a peculiar manner from the twigs
of certain species of _Rhamnus_. According to report, the bark is
boiled with water and a cotton cloth immersed in the decoction. The
fibre fixes a colourless substance which becomes green on exposure to
air. The cotton is repeatedly dipped into the decoction until it has
absorbed a large quantity of colouring matter. It is then washed with
cold water and boiled with water upon which cotton yarn is laid. The
colouring matter suspended in the liquid adheres to the yarn, which
is washed with a little cold water, and the colouring matter then
collected upon paper and dried.
If Chinese green is really made by this process, it is not a lake but
a vegetable colouring matter, to which clay has been added to increase
its weight or to make it plastic. Very fine lakes can be obtained from
Chinese green by dissolving it in a solution of alum, and adding soda
solution. When Chinese green is dissolved in acetic acid and ammonium
chloride and a zinc salt added, a blue lake is produced on the further
addition of sodium acetate. A bluish violet lake is obtained by
treating Chinese green with a strong reducing agent and adding calcium
acetate.
=Charvin’s Green.=—The very high price at which genuine Chinese green
was sold whilst it was still a novelty, gave rise to attempts at
imitation. Charvin, of Lyons, succeeded in producing a pigment from
_Rhamnus_ which has the characteristic property of Chinese green of
retaining its colour in artificial light. He plunged the bark of common
buckthorn into boiling water, boiled for a few minutes, and allowed
the whole to stand for twenty-four hours. Lime water was added to the
brown liquid, which was then exposed to the action of the air in
shallow vessels, when it gradually turned green and deposited a green
precipitate. When this appeared, the liquid was brought into glass
vessels and potassium carbonate solution added so long as a precipitate
resulted, which after drying had all the properties of genuine Chinese
green.
Although for some time Chinese green was a very fashionable colour, its
use is now almost discontinued, although it can be used with advantage
as an artists’ pigment, and its preparation by Charvin’s method is
neither difficult nor specially costly.
CHAPTER LXIV.
BROWN ORGANIC PIGMENTS.
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