The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments — John Shaqi
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Although at present in commerce the strength of potashes is frequently
guaranteed, it is still desirable to estimate the strength. It is
sufficient for practice to allow a small quantity, say 100 grammes, to
stand with an equal quantity of very cold water for some hours, then
to filter and pour a similar quantity of water over the residue on
the filter. The weight of undissolved substance subtracted from 100
gives with sufficient accuracy the weight of pure potassium carbonate
contained in 100 parts of potashes. This method is founded on the fact
that potassium carbonate dissolves readily even in cold water, but the
other salts with difficulty. This procedure can also be used to obtain
pure potassium carbonate from crude potashes; it is only necessary to
filter and evaporate to dryness the solution obtained by pouring very
cold water on crude potashes.
=Potassium Hydroxide= (Potassium Hydrate, Caustic Potash), KOH =
56.—The commercial variety consists of very deliquescent white lumps,
generally containing a large quantity of impurities. On this account
caustic potash, or rather a solution of it, is prepared in the colour
works.
With this object 11 parts of potash, contained in a tub with an opening
at the bottom, are mixed with 100 parts of cold water. Two hours
later, the clear solution is run off into a clean iron pan, in which
it is heated to boiling. To the boiling solution is added milk of
lime prepared from water and 3·5 parts of quicklime. After the liquid
has boiled a few minutes, a small portion is filtered and hydrochloric
acid added to the clear filtrate; if no effervescence occurs, then
all the potassium carbonate is converted into caustic potash. Should
effervescence occur, milk of lime is added until a new portion no
longer effervesces on the addition of hydrochloric acid. Then the pan
is covered with a well-fitting lid, and the cooled liquid, if not
required for immediate use, preserved in well-corked glass bottles.
The strength of a caustic potash solution can be found by means of a
hydrometer. The following table shows the relation between the specific
gravity of a solution and the percentage of caustic potash it contains:—
+----------+----------------+
| Specific | Caustic Potash |
| Gravity. | per cent. |
+----------+----------------+
| 1·06 | 4·7 |
| 1·11 | 9·5 |
| 1·15 | 13·0 |
| 1·19 | 16·2 |
| 1·23 | 19·5 |
| 1·28 | 23·4 |
| 1·39 | 32·4 |
| 1·52 | 42·9 |
| 1·60 | 46·7 |
| 1·68 | 51·2 |
+----------+----------------+
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