The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
2. In the above methods the manufacture of white lead commences with
the production of white lead from metallic lead and acetic acid. In the
so-called French method a solution of basic lead acetate is decomposed
by carbonic acid into white lead and neutral lead acetate, which latter
is again converted into basic acetate.
3. The English method. The principle of this process consists in
moistening litharge with a solution of lead acetate and exposing it to
the action of carbonic acid, whereby white lead is formed.
Methods for manufacturing white lead, which are often advanced as
entirely new processes, may be always traced to one of the above, from
which they deviate but little in principle, and the deviations cannot
always be regarded as improvements. In the following detailed account
of the manufacture of white lead we shall adhere to the classification
just given, according to which there are three principal methods: (1)
Manufacture of white lead from metallic lead, acetic acid and carbonic
acid (Dutch and German processes); (2) manufacture of white lead from
basic lead acetate (French process); and (3) from litharge moistened
with lead acetate solution (English process).
We should remark that every year “new” processes for the manufacture of
white lead are patented. The majority of these will not be mentioned;
to those acquainted with the principles of chemistry they at once
appear impracticable.
MANUFACTURE OF WHITE LEAD FROM METALLIC LEAD.
(a) DUTCH PROCESS.
This essentially primitive process, when properly conducted, produces
white lead of good colour and covering power, which are the properties
for which this pigment is valued. It is now seldom used,[2] because
other methods give a product of equal colour in a shorter time. It is,
however, of economic interest, as showing how a branch of industry
may rise from crude beginnings to a high state of perfection. The
operations comprised in the Dutch process are as follows:—
[2] In England the Dutch process is in general use.—TRANSLATOR.
(1) Casting the lead into sheets; (2) placing these sheets in pots and
arranging the pots in the stacks (placing the pots containing lead
and acetic acid in the bed of manure); (3) removing the pots from the
stack; (4) separating the white lead formed in the pots; (5) further
purification of the impure white lead by grinding, washing and drying.
1. =Casting the Lead into Sheets.=—At first sight it would appear
unsuitable to cast lead in sheets, since this metal can be readily
rolled into sheets of any thickness. Experience has, however, shown
that rolled lead is only slowly attacked by acetic acid vapours, whilst
cast sheets are rapidly attacked.
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