The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
When bark is used in place of manure, a discolouration of white lead by
sulphuretted hydrogen is not to be feared, but there is the drawback
that a longer time is necessary for the corrosion of the lead, because
the bark decomposes more slowly than the manure, and accordingly gives
out less heat and carbonic acid.
According to the climate of the country, the stacks may be differently
erected. In colder countries it is necessary to sink them in the earth
and surround them with masonry, as directed above; but in warmer
climates such effectual protection against cooling is unnecessary, yet
in all cases it is better to sink the stack in the earth on account of
the regularity of temperature so obtained.
Instead of sinking the stacks in the earth, they may be built in the
open when there is a plentiful supply of manure or bark; but they must
then be surrounded by a very thick layer of manure to prevent cooling.
It is a desirable alteration in the construction of the stacks to
provide the pots with lids, and so avoid the use of the layer of boards
separating each two layers of pots. The object of the cover is simply
to prevent dirt from falling into the pot. It should not fit tightly on
the edge, or the entry of carbonic acid into the interior of the pot
would be made difficult. The lids are therefore rounded and fit loosely
on the pot. When pots with lids are used, the lowest layer is covered
with manure in the ordinary way; upon this again comes a layer of pots,
and so on.
The transformation of the lead may be regarded as complete in four
to six weeks when manure is used, but with bark the time extends to
ten weeks. The quantity of white lead obtained varies in different
cases; for example, from a stack 5 metres long, 4 metres wide, and 6
metres high, into which 12,000 kilogrammes of lead were put, 10,000
kilogrammes of white lead were obtained, and 4,000 kilogrammes of
lead remained unaltered. In another case, for a stack of 8 layers 280
kilogrammes of vinegar and 9,600 to 12,000 kilogrammes of lead were
used, and there was a residue of 10 to 15 per cent. of lead.
3. =Removal and Grinding of the White Lead.=—The stack is pulled down
after the lapse of the necessary time; the lead plates and rolls are
collected in wooden boxes and brought into the room where the white
lead is separated from the metallic lead. Formerly the white lead was
removed from the sheets exclusively by manual labour, an operation
extremely dangerous to the workman. It is quite impossible to prevent
the formation of white lead dust, so that the men were continuously
in an atmosphere charged with the poisonous material, and, as a
consequence, suffered from the various forms of lead poisoning.
In order to diminish as much as possible the injurious effects of white
lead on the health of the workmen, manual labour has been, as far as
possible, replaced by machinery, yet the greatest care is necessary in
the different manipulations of so poisonous a substance as white lead.
Public-domain text, read in full here on John Shaqi.
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