The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
The stack consists of a rectangular pit walled on three sides; the
fourth side is open, with the earth dug out in the form of an inclined
plane, in order to permit the introduction of the pots and the manure.
The construction of the stack is commenced by placing the pots at the
bottom in rows, avoiding interspaces as much as possible. In a stack of
the size mentioned a layer contains 1,000 to 1,200 pots. Between the
pots containing lead and acetic acid are arranged a number of larger
ones containing acid only; the object of these is to furnish acetic
acid vapour. When the pots are in place, 3 or 4 lead plates are placed
on each spiral, the top plate forming the cover; immediately over the
pots strong wooden planks are laid, and upon them a layer of boards,
which must fit so tightly that nothing can fall through. On the boards
is spread out a layer of fresh stable manure, with which the space
between the outside row of pots and the wall is also filled. The layer
of manure is 30 to 40 centimetres thick.
Upon the lowest layer of pots, a second, third and so on are built up
exactly in the same manner, so that the whole stack is filled with
alternating layers of pots and manure. In order to prevent the cooling
of the uppermost layer of pots, it is covered with a thicker layer of
manure 60 to 70 centimetres thick. When lead plates and the taller pots
are used, a stack will generally contain 15 layers; but when gratings
and the smaller pots are employed, 18 layers can be packed into the
same space. In arranging the layers of pots, care should be taken to
leave spaces at tolerably equal distances, so that the air necessary
for the oxidation of the lead may enter. To prevent the cooling of the
stack at the front, where it is not protected by masonry, when full it
is walled up with boards; a board roof also protects the erection from
rain.
In place of manure, spent tanners’ bark can be used, which in the
same manner ferments, producing heat and carbonic acid. In places in
the neighbourhood of large tanneries this spent bark is generally
obtainable at lower prices than stable manure, which is more valuable
for agricultural purposes; the former has also a very considerable
advantage, white lead made by means of spent tanners’ bark being
generally of a purer white than that made with manure. The reason for
this is that in the decomposition of animal excrement small quantities
of sulphuretted hydrogen are produced, a gas which produces black lead
sulphide when it comes into contact with lead compounds.
According to the results of practical experience, pigs’ dung cannot be
used in the manufacture of white lead; so much sulphuretted hydrogen
is evolved from it that the white lead is not white, but has a greyish
tinge.
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