The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
In working with metallic lead, this must be used in a finely divided
form; it is cast, as in the Dutch process, into thin sheets or
gratings, or into flat wires or ribbons. These ribbons are easily
made by melting the lead in a pan provided with a delivery pipe with
stop cock; beneath the latter is brought a vessel, which can be moved
backwards and forwards upon a tram line, filled with water. When the
melted lead is allowed to flow into this vessel, which is being moved
backwards and forwards, the metal forms long, thin ribbons, which
possess a large surface. A wooden tub is almost completely filled with
these lead ribbons, which are then covered with acetic acid. After a
short time the acid is run off, when, by the action of the air, so
energetic an oxidation of the lead takes place that the contents of the
tub become heated, and steam and acetic acid vapours begin to rise.
When this is seen, the original acetic acid is pumped back into the
tub, and left there for some hours in contact with the lead in order
that it may dissolve the lead oxide. When the solution has reached
a specific gravity of 1·1326 to 1·1415, it is drawn off from the
undissolved lead, which again, in a short time, in consequence of the
rapid oxidation, becomes warm, and is treated with fresh acetic acid.
The lead ribbons become finally so thin that they fall together by
their own weight, and form tight masses, upon which air and acetic
acid can no longer act. These residues are then removed from the
solution vessel and new ribbons introduced. The residues have a velvety
appearance; when they are mixed up with water they make it dark, and
from the turbid liquid a fine, velvet-black powder soon separates,
which consists of finely divided silver. The liquid still remains
turbid owing to the suspension of fine particles of carbon. The lead
ores, especially galena, often contain notable quantities of silver;
silver lead is generally desilverised before use; usually, however,
small quantities of silver remain in the lead. When the lead is
dissolved in acetic acid, this silver settles as a soft powder at the
bottom of the vessels in which the lead residues from the solution tubs
are washed.
2. =Preparation of the Carbonic Acid and Precipitation of the White
Lead.=—The carbonic acid required for precipitating the basic carbonate
is obtained either by heating limestone in a small furnace, from which
the gas is drawn by a pump, or directly by burning charcoal. In the
former case very pure carbonic acid is obtained, and, as a by-product,
valuable quicklime; in the latter case precautions must be taken to
produce pure carbonic acid.
[Illustration: FIG. 16.]
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