The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
If a special apparatus is not provided, as it should be, on the large
scale, to separate the unaltered lead from the white lead, the lumps
coming from the chambers must be subjected to a process of levigation,
in which the lead, being the heaviest body, will be first deposited;
the last portions deposited consist of the purest white lead, the lower
layers of which will be tinged more or less grey by an admixture of
finely divided lead and lead peroxide.
White lead manufactured by the German process occasionally exhibits
perceptible reddish or greyish tinges, the cause of which lies in the
defective execution of the process. The red tinge denotes the presence
of free lead oxide, caused by the use of an insufficient quantity of
acetic acid. A grey tint is due to the presence of metallic lead or an
excess of lead carbonate.
(c) FRENCH PROCESS.
The French process for making white lead is based upon the reaction
which occurs when carbonic acid is passed into a solution of basic lead
acetate; basic lead carbonate is precipitated and neutral lead acetate
remains dissolved; the latter is again converted into basic acetate,
from which carbonic acid again separates white lead and so on. This
process, at present used on an enormous scale, is due to the French
chemist Thénard, who first put it into operation on the large scale at
Clichy, near Paris. The method is also known as the Clichy process.
The operations of this process are divided into the production of the
basic acetate and the treatment of its solution with pure carbonic
acid, whereby the basic carbonate is precipitated.
1. =Preparation of the Solution of Basic Lead Acetate.=—The preparation
of this compound has been already described; the following is
supplementary to what was previously given. If litharge be used, it is
dissolved in wooden tubs heated by steam. The acetic acid is brought
nearly to boiling by open steam, and the finely ground litharge
gradually added. In consequence of its high specific gravity, the
litharge would quickly sink to the bottom, so that it is advisable
to keep the liquid in motion by means of a stirrer, and to allow the
litharge to fall in in a thin stream. The introduction of the latter is
continued until the specific gravity of the solution indicates that the
liquid contains three equivalents of lead oxide to one equivalent of
acetic acid.
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