The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
Just as the quantities of the solutions used and their strength
influence the shade of the chrome yellow they produce, so it also
appears to be not immaterial which lead salt is employed. Colour makers
are generally agreed that the finest product is obtained from neutral
lead acetate. Any lead salt, even insoluble in water, may be used for
the preparation of chrome yellow. The affinity of chromic acid for
lead is so great that an interchange of constituents occurs between
the insoluble salt and the potassium chromate. Chrome yellow may be
made from lead acetate, chloride or sulphate; the resulting substances
are the same, but there is a considerable difference in regard to the
beauty of the product. The finest chrome yellow, which leaves nothing
to be desired in beauty of shade, is obtained by proceeding in the
following manner: Lead acetate is dissolved in water, the solution
diluted with an equal volume of water, and then mixed, under constant
stirring, with a similarly diluted solution of potassium chromate or
bichromate. The precipitate is immediately formed, and quickly sinks to
the bottom in consequence of its high specific gravity. It is washed
with clean water so long as this removes soluble salts. The precipitate
is then drained on cloths and dried in the air.
The finest product is obtained by working with the following
proportions:—
Sugar of lead 100
Potassium bichromate, or 50
Potassium chromate 40
If lead sulphate is used the following quantities are to be employed:—
Lead sulphate 100
Potassium bichromate 25
In the case of lead chloride the following is the proportion:—
Lead chloride 100
Potassium bichromate 27
The chrome yellows prepared from insoluble lead salts have no
particular beauty, but they may be used for mixed colours such as the
spurious chrome green.
=Preparation of the Lead Solution.=—Many makers of chrome yellow do not
use commercial lead acetate, but prepare its solution themselves. The
preparation of this solution requires neither much space nor labour, so
that considering the high price of lead acetate this procedure may be
regarded as advisable, but only when acetic acid is obtainable at a low
rate.
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