The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigmentsBersch, Josef
Science
The manufacture of mineral and lake pigments : $b Containing directions for the manufacture of all artificial artists' and painters' colours, enamel colours, soot and metallic pigments
Bersch, Josef
Dyes and dyeing; Pigments
=Neutral Lead Chromate=, PbCrO₄, is formed as a very heavy precipitate
of a fine deep yellow colour when a solution of potassium chromate or
bichromate is added to a solution of a lead salt in water. When exactly
equivalent quantities of potassium chromate and lead solution are used,
and the strength of the solutions is the same, the product has the
same shade each time the operation is performed. It is not immaterial
whether the one or the other salt is in excess, or whether strong or
weak solutions are used; all these conditions modify the shade of
the chrome yellow produced. Many colour makers are apparently of the
opinion that some particular skill of the workman is necessary to
produce chrome yellow of a particular shade. This is, however, not the
case; manufacturers who know the simple conditions which are important
in making chrome yellows may produce any desired shade without
difficulty.
Neutral lead chromate readily parts with half the chromic acid it
contains. When treated with alkalis, such as lime or caustic soda, or
even when digested with finely ground litharge, the neutral salt gives
up half of its chromic acid, and is converted into the basic chromate
or chrome red, Pb₂CrO₅.
Basic lead chromate has, as the name chrome red indicates, a fine red
colour. If the quantity of lime or caustic soda used is sufficient to
decompose only a portion of the neutral lead chromate, a mixture of the
yellow neutral and the red basic chromate is formed, the shade of which
will incline to yellow or red according as it contains a preponderance
of one or the other compound. The pigment known as orange chrome is
a mixture of approximately equal parts of the neutral and basic lead
chromates.
In order to brighten the deep yellow shade which distinguishes
neutral lead chromate, it is either mixed with a white pigment, or
a white substance (lead sulphate) is precipitated from the solution
simultaneously with the lead chromate. In this manner all the
imaginable pale yellow shades, lemon yellow, sulphur yellow, etc., can
be obtained.
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