The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
It occurs naturally in a variety of forms, such as gypsum, alabaster,
selenite, the first of which when finely powdered is sold to the
paper-maker as gypsum, powdered plaster, and under other fancy names.
It can be prepared artificially by adding sulphuric acid to solutions
of calcium salts; and the precipitated product so obtained is sold as
terra alba, pearl hardening, satinite, mineral white, etc.
The tests for sulphate of lime in paper ash are based upon the
following reactions:--
Calcium sulphate is soluble in dilute hydrochloric acid. The addition
of a few drops of barium chloride to the solution produces a dense
heavy precipitate, indicating the sulphate. A small quantity of
ammonium oxalate solution added to another portion of the dissolved
calcium salt previously neutralised with ammonia produces a precipitate
and indicates calcium.
A microscopic test of paper for the presence of sulphate of lime is
based upon the slight solubility of the salt in water. The paper is
boiled with some distilled water. The water is evaporated to a small
bulk and transferred to a glass slip, and the gradual formation of
characteristic sulphate of lime crystals can be seen by means of the
microscope as the water cools down.
_French Chalk._--This material is prepared by grinding talc into a
fine powder, and possesses a good colour and a somewhat soapy feel. It
is a silicate of magnesia, having the approximate composition--
Silica (SiO_{2}) 62·00
Magnesia (MgO) 33·00
Water 4·30
Traces of oxides, etc. 0·70
------
100·00
Other silicates of magnesia used for paper-making are agalite and
asbestine, the latter being a finely ground asbestos.
The composition of asbestos is approximately--
---------------------------+----------+-----------
-- | Italian. | Canadian.
---------------------------+----------+-----------
Lime and magnesia | 38·0 | 33·0
Silica | 42·0 | 41·0
Oxides of iron and alumina | 5·0 | 12·0
Total water | 13·0 | 12·0
Traces of soda, etc | 2·0 | 3·0
+----------+-----------
| 100·00 | 100·00
---------------------------+----------+-----------
CHAPTER IX
THE PROCESS OF BEATING
_Introduction._--The process of beating has for its object the complete
breaking down of the bleached pulp to the condition of single fibres,
and the further reduction of the fibres, when necessary, into smaller
pieces. The disintegration of the material is essential for the
production of a close even sheet of paper, and the amount of beating
required varies greatly according to the nature of the raw material,
and the class of paper to be produced.
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