The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
_Examination of Paper for Loading._--If a piece of paper is crumpled
up, placed in a small crucible, and then ignited until all the
carbonaceous matter has been burnt off, a residue is left in the
crucible which may be white or coloured. This is usually termed the
_ash_ of the paper. The amount of ash present is determined by taking
a weighed quantity of paper and weighing the residue obtained. Special
appliances can be obtained for making rapid determinations of the ash
in paper, but for occasional analyses they are not required.
_China Clay._--This is the best known and most commonly used loading.
The purest form of this material is kaolin, a natural substance formed
by the gradual decomposition of felspathic rocks arising from exposure
to the long-continued action of air and water. The clay occurs in great
abundance in Dorset, Cornwall, and Devon, the southern counties in
England, where the most famous deposits are found.
The natural mineral is levigated with water, and the mixture allowed
to flow through a series of settling ponds, so that the clay gradually
settles in the form of a fine deposit. The clay is dried and packed
in bags. Its value is controlled largely by the purity of its colour
and its freedom from grit and sand. It is essentially a silicate of
alumina, having the approximate composition--
Silica (SiO_{2}) 43·00
Alumina (Al_{2}O_{3}) 35·00
Combined water 10·00
Moisture and impurities 12·00
------
100·00
The specific gravity of the dry substance is 2·50.
It is utilised as a loading in all kinds of paper, and forms also the
main ingredient in the coating found on ordinary art and chromo papers.
_Ash containing China Clay._--In news, cheap printings, and common art
papers the ash almost invariably contains china clay. This substance is
insoluble in dilute acids, but is acted upon by concentrated sulphuric
acid when digested for some time. A simple test for the presence of
china clay in ash is the blue coloration which is obtained when the ash
after being ignited is gradually heated with a few drops of solution of
cobalt nitrate. China clay can be decomposed by fusion with carbonate
of soda in a crucible. By this means silicate of alumina is decomposed,
and the alumina goes into solution, the silica remaining as an
insoluble residue. The filtered solution is boiled with an excess of
ammonia which gives a gelatinous precipitate of aluminium hydrate.
_Sulphate of Lime._--This compound is valued chiefly for its brilliancy
of colour, being used in high-class papers. It is slightly soluble in
water, to the extent of about 23 lbs. in 1,000 gallons, and this fact
must be taken into account when the material is added to the pulp in
the beating engine.
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