The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
The under surface of the paper is not invariably darker than the top
surface. With pigments of less specific gravity the reverse is found to
be the case. This is probably to be explained by the fact that some of
the colouring matter from the under side is drawn away from the paper
by the suction boxes, and the pigment on the top side is not drawn away
to any serious extent, because the layer of pulp below it acts as a
filter and promotes a retention of colour on the top side.
It is interesting to notice that this irregularity sometimes occurs
with soluble dyes, as for example in the case of auramine. The
decomposition of this dye when heated to the temperature of boiling
water is well known, and the contact of a damp sheet of paper coloured
by auramine with the surfaces of steam-heated cylinders at a high
temperature brings about a partial decomposition of the dye on one side
of the paper. Generally speaking, acid dyes are more sensitive to heat
than basic dyes.
The presence of china clay in a coloured paper is also an explanation
of this irregular appearance of the two sides. China clay readily forms
an insoluble lake with basic dyes, and when the suction boxes on the
machine are worked with a high vacuum the paper is apt to be more
deeply coloured one side than another.
_The Machine Backwater._--Economy in the use of dyes to avoid a loss
of the colouring matter in the "backwater," or waste water from the
paper machine, is only obtained by careful attention to details of
manufacture on the one hand and by a knowledge of the chemistry of
dyeing on the other. The loss is partly avoided by regulating the
amount of water used on the machine, so that very little actually goes
to waste, and further reduced by ensuring as complete a precipitation
of the soluble dye as possible.
The _acid_ dyes generally do not give a colourless backwater, and all
pulps require to be heavily sized when acid dyes are used.
The _basic_ dyes are more readily precipitated than the acid dyes,
particularly if a suitable mordant is used, even with heavily coloured
papers. The addition of an acid dye to pulp first coloured with a basic
dye is frequently resorted to as a means of more complete precipitation.
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