The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
_Dyeing to Sample._--The matching of colours has been greatly
simplified through the publication of pattern books by the firms who
manufacture dyes, in which books full details as to the composition
of the paper, the proportion of colour and the conditions for maximum
effects are fully set out. The precise results obtained by treating
paper pulp with definite proportions of a certain dye, or a mixture
of several dyes, is determined by experimental trials. A definite
quantity of moist partially beaten and sized pulp, containing a known
weight of air-dry fibre, is mixed with a suitable volume of water at a
temperature of 80° to 90° F. and the dye-stuff added from a burette in
the form of a 1 per cent. solution. If preferred a measured volume of
a 1 per cent. solution of the dye can be placed in a mortar, and the
moist pulp, previously squeezed out by hand, added gradually and well
triturated with the pestle.
The dyed mixture is then suitably diluted with water, made up into
small sheets of paper on a hand mould or a siphon mould, and dried.
The effect of small additions of colour to the contents of a beating
engine is frequently examined in a rough and ready way by the
beaterman, who pours a small quantity of the diluted pulp on the edge
of the machine wire while the machine is running. This gives a little
rough sheet of paper very quickly.
The comparison of the colour of a beaterfull of pulp with the sample
paper which it is desired to match is also effected by reducing a
portion of the paper to the condition of pulp, so that a handful of the
latter can be compared with a quantity of pulp from the engine. This is
not always a reliable process, especially with papers coloured by dyes
which are sensitive to the heat of the paper machine drying cylinders.
_Detection of Colours in Papers._--The examination of coloured papers
for the purpose of determining what dyes have been employed is a
difficult task. With white papers which have been merely toned the
proportion of dye is exceedingly small, and a large bulk of paper has
to be treated with suitable solvents in order to obtain an extract
containing sufficient dye for investigation.
With coloured papers dyed by means of pigments, the colour of the
ash left on ignition is some guide to the substance used, a red ash
indicating iron oxide, a yellow ash chromate of lead, and so on.
With papers dyed by means of coal tar colours the nature of the
colouring matter may be determined by the methods of analysis employed
for the examination of textile fibres.
The following hints given by Kollmann will be found useful:--
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