The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
Tear up small about 100 grammes of paper, and boil it in alcohol, in
a flask or a reflux condenser. This must be done before the stripping
with water, so as to extract the size which would otherwise protect
the dye from the water. Of course the alcohol treatment is omitted
with unsized paper. The paper is now boiled with from three to five
lots of water, taking each time only just enough to cover the paper.
This is done in the same flask after pouring off any alcohol that
may have been used, and also with the reflux condenser. The watery
extract is mixed with the alcohol extract (if any). Three cases may
occur:--(1) The dye is entirely stripped, or very nearly so. (2) The
dye is partly stripped, what remains on the fibres showing the same
colour as at first or not. (3) The dye is not stripped. To make sure
of this the solution is filtered, as the presence in it of minute
fragments of fibre deceive the eye as to the stripping action. In the
first two cases the mixed solutions are evaporated down to one half on
the water bath, filtered, evaporated further, and then precipitated by
saturating it with common salt. The dye is thrown out at once, or after
a time. It may precipitate slowly without any salt. The precipitated
dye is filtered off and dried. To see whether it is a single dye or a
mixture, make a not too dark solution of a little of it in water, and
hang up a strip of filter paper so that it is partly immersed in the
solution. If the latter contains more than one dye they will usually
be absorbed to different heights, so that the strip will show bands of
different colours crossing it. If it is found that there is only one
dye, dissolve some of it in as little water as possible, and mix it
with "tannin-reagent," which is made by dissolving equal weights of
tannin and sodium acetate in ten times the weight of either of water.
If there is a precipitate there is a basic dye, if not, an acid dye.
In the former case mix the strong solution of the dye with concentrated
hydrochloric acid and zinc dust, and boil till the colour is destroyed.
Then neutralise exactly with caustic soda, filter, and put a drop of
the filtrate on to white filter paper. If the original colour soon
reappears on drying, we draw the following conclusions:--
(_a_) The colour is red; the dye is an oxazine, thiazine, azine, or
acridine dye, _e.g._, safranine. (_b_) It is orange or yellow; the dye
is as in (_a_), _e.g._, phosphine. (_c_) It is green; the dye is as in
(_a_), _e.g._, azine green. (_d_) It is blue; the dye is as in (_a_),
_e.g._, Nile blue, new blue, fast blue, or methylene blue. (_e_) It
is violet; the dye is as in (_a_), _e.g._, mauveine. If the original
colour does not reappear on drying, but does so if padded with a 1 per
cent. solution of chromic acid, we draw the following conclusions:--
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