The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
They are based upon the principle of mixing chemicals with the water
to be treated, so as to precipitate the matters in solution and
give a boiler feed-water free from carbonates and sulphates of lime
and magnesia. The chemicals are added in the form of solutions of
carefully regulated strength to the water, which flow in a continuous
stream into a tank. The flow of the water and chemical reagent is
adjusted by previous analysis.
The various machines differ in details of construction, and in the
methods by which the mixing of the water and reagents is effected. The
object to be achieved is the complete precipitation of the dissolved
salts and the production of a clear water, free from sediment, in an
apparatus that will treat a maximum quantity of water at a cheap rate
per 1,000 gallons.
The process needs proper attention. The addition of reagents in
wrong proportions will do more harm than good, and possibly result
in hardening the water instead of softening it. The following may be
quoted as an example:--
----------------------+-----------+-----------+------------
Composition of Water. | Before | After | Change.
| Treatment.| Treatment.|
----------------------+-----------+-----------+------------
Calcium carbonate | 13·863 | 38·920 | 25·057 gain
Calcium oxide (lime) | 0·0 | 14·300 | 14·300 "
Calcium silicate | 2·062 | 3·591 | 1·529 "
Calcium sulphate | 1·625 | 2·121 | 0·496 "
Magnesia | 0·0 | 0·266 | 0·266 "
Ferric oxide, etc. | 0·447 | 0·987 | 0·540 "
+-----------+-----------+------------
Scale forming mineral| 17·997 | 60·185 | 42·188 gain
+-----------+-----------+------------
Calcium chloride | 1·331 | 2·114 | 0·783 gain
Magnesium chloride | 0·672 | 0·0 | 0·672 loss
Sodium chloride | 0·478 | 0·476 | 0·003 "
+-----------+-----------+------------
Soluble salts | 2·482 | 2·590 | 0·108 gain
+-----------+-----------+------------
Total mineral matter | 20·479 | 62·776 | 42·297 gain
+-----------+-----------+------------
Carbonic acid gas | 9·71 | 0·0 | 9·71 loss
Oxygen gas | 0·66 | 0·66 | 0·0 "
----------------------+-----------+-----------+------------
Treatment required: 1·8 lbs. of lime, 0·2 lbs. soda ash per 1,000
gallons. Apparently 5·5 lbs. of lime were being used and no soda
(Stromeyer).
Public-domain text, read in full here on John Shaqi.
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