The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
The artist is frequently compelled in such cases to put a layer of
heavy white colour on the sheet of paper before proceeding to paint the
picture.
The storage of books under favourable conditions has a great deal to
do with the permanence of the paper, and the degradation of a paper in
relation to the tub-sizing qualities is much hastened by the presence
of moisture in the air.
_Starch._--The same is true of starch, which is largely employed as
a binding or sizing material in paper. The degradation of gelatine,
starch, and similar nitrogenous substances is due to the action of
organisms, and the following experiments, suggested by Cross, are
interesting in this connection.
If strips of paper are put into stoppered bottles with a small quantity
of warm water and kept at a temperature of about 80° F., fungus
growths will be noticed on some of them after the lapse of fourteen
days. Rag papers sized with gelatine will show micro-organisms of all
kinds. A pure cellulose paper, like filter paper, will not produce any
such effects. The result in the first case is due to the nitrogenous
substance, viz., the gelatine used in sizing, since the two papers
are identical as far as the cellulose fibres are concerned. High-class
wood pulp papers, unless sized with gelatine, would not show similar
results. The action of the organisms upon the nitrogenous material by a
process of hydrolysis is in the direction of the production of soluble
compounds allied to the starch sugars capable of being assimilated by
organisms.
The cellulose of esparto and straw are readily attacked, and it is
on this account that the tissues of the various straws are digested
more or less when eaten by animals. It is for this reason that the
celluloses from straw and esparto are inferior to the cotton cellulose
in producing a paper likely to be permanent.
_Chemical Residues._--The necessity for manufacturing a pure cellulose
half-stuff is fully recognised by paper-makers. This was not the case
in the early days of the manufacture of wood pulp, for it is a matter
of common experience that many of the books printed on wood pulp paper
between 1870 and 1880 are in a hopeless condition, and it is quite easy
to find books and periodicals of that date the pages of which crumble
to dust when handled. This serious defect has been proved to be due to
the presence of traces of chemicals used in manufacture which have not
been thoroughly removed from the pulp.
The precautions necessary in bleaching pulp by means of chloride of
lime, in order to prevent (1) any action between the fibre and the
calcium hypochlorite, (2) the presence of residual chlorine or soluble
compounds derived from it, and (3) the presence of by-products arising
from the use of an antichlor, are also well known to paper-makers. The
subject has been closely studied by chemists, who have shown that the
deterioration of many modern papers may be ascribed to carelessness in
bleaching.
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