The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
The questions relating to the chemical residues of paper can only be
adequately dealt with by a discussion of actual cases which arise from
time to time. There are certain conditions in manufacture, common to
all papers, which may give rise to the presence of chemical residues,
of which two have already been mentioned.
The acidity of papers is frequently quoted as an instance. It is true
that the presence of free acid in a paper is most undesirable, as it
seriously attacks the cellulose, converting it into an oxidised form.
This in course of time renders the paper so brittle as to destroy its
fibrous character.
The change is brought about by the acid, which itself suffers no
material alteration, so that the process of deterioration is continued
almost indefinitely until the cellulose is completely oxidised. Most
papers, however, show an acid reaction when tested with litmus, the
usual reagent employed by those not familiar with the proper methods
of testing paper. All papers which have been treated with an excess
of alum for sizing purposes would show an acid reaction with litmus
without necessarily containing any free acid.
The presence of iron is undesirable, particularly in photographic
papers, and since cellulose has a remarkable affinity for iron, the
conditions of manufacture which tend to leave iron in the pulp have to
be taken into consideration. The presence of minute quantities of iron
in the form of impurities must not be confused with the presence of
iron in large quantities derived from the toning and colouring of paper
by means of iron salts.
The fading of colour is frequently observed when coloured papers are
tested on boxboards, particularly those made of straw. This fading may
often be traced to the presence of alkali in the straw board which has
not been completely removed in the process of manufacture.
The blurring of letterpress is a defect which often occurs with
printing papers made of chemical wood pulp. The oil in the ink
seems to separate out on either side of the letter, producing a
discoloration. In such cases the paper itself frequently exhibits an
unpleasant smell.
These defects are usually determined by the presence of traces of
sulphur compounds in the paper resulting from incomplete washing of
the pulp in manufacture. The presence of sulphur compounds sometimes
associates itself with papers which have been coloured by means of
ultramarine, which in presence of alum is slightly decomposed by the
heat of the drying cylinders.
Some knowledge of the effect of chemical residues in paper is
important, not only in regard to the deterioration which takes place
in the fibre itself, but also in relation to the fading of the ink
which is used. The subject of the ink has received much attention
from chemists on account of the serious difficulties which have been
experienced by State departments in various countries.
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