The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
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The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
CELLULOSE ACETATE (Cross).--If cellulose is heated with acetic
anhydride at 180° C., viscous solutions of the acetates are
obtained. The process yielding a definite acetate of commercial
value is based upon the following reaction:--100 parts of
cellulose prepared from the sulpho-carbonate are mixed with
120 parts of zinc acetate, heated and dried at 105° C. Acetic
anhydride is added in small quantity, and 100 parts of acetyl
chloride. At a temperature of 50° C. the mixture becomes liquid,
and cellulose acetate is subsequently obtained as a white powder.
The compound can be used in the place of cellulose nitrate, and,
being non-explosive, may gradually replace the latter in many
industrial applications.
_Cellulose-Benzoate._--When alkali cellulose is heated with benzoyl
chloride and excess of caustic soda, this substance is obtained.
_Cellulose Hydrate._--The substances produced by the action of acid
and alkali on cellulose under certain strictly defined conditions
are bodies containing cellulose united with water to form
hydrates. The industrial applications of cellulose based upon
this reaction are described under the special headings.
CELLULOSE NITRATE.--A considerable number of derivatives are obtained
by bringing cellulose into contact with nitric acid. Variations
in the strength of the acid, the temperature of reaction, and the
time of contact determine the nature of the product. The best
known nitrates are:--
Cellulose di-nitrate.
Cellulose tri-nitrate and tetra-nitrate, present chiefly in
pyroxyline.
Cellulose penta-nitrate.
Cellulose hexa-nitrate, the chief constituent of gun-cotton.
CHARCOAL.--Not a cellulose derivative in the strict sense of the
term, charcoal being a residue obtained in the dry distillation
of wood.
COLLODION.--A soluble nitrate of cellulose used in photography. (See
Pyroxyline.)
CORDITE.--A smokeless powder consisting mainly of nitro-glycerine
and gun-cotton mixed with acetone. The materials are thoroughly
incorporated and the resultant paste formed into threads which
are dyed and then cut up into suitable lengths for cartridges.
_Cuto-Cellulose._--Synonymous with adipo-cellulose.
_Dextron._--A compound prepared from the waste liquors of the
bisulphite process used for the manufacture of wood pulp.
Resembles dextrin in its physical properties.
DEXTROSE.--A carbohydrate which can be obtained by the action of
mineral acids on cellulose. Commercial dextrose, or glucose, is
prepared by the conversion of starch with sulphuric acid. The
starch is mixed with dilute acid at a fixed temperature, and the
starch milk obtained poured gradually into a vessel containing
dilute acid, which is maintained at boiling point. The conversion
is complete and rapid.
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