The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
_Oxy-Cellulose._--A white friable powder produced by treating
cellulose with nitric acid at 100° C. The oxidation of cellulose
is brought about by several reagents such as chromic acid,
hypochlorites of lime and soda, chlorine, and permanganates. The
extent to which cloth has been damaged by overbleaching may be
determined by a simple test with methylene blue solution, which
is readily absorbed by oxy-cellulose present in such fabrics.
PARCHMENT.--A tough paper prepared by the action of sulphuric acid on
unsized paper. (See page 137.)
_Pectins._--(See Pecto-Cellulose.)
_Pecto-Cellulose._--A generic term applied to many important fibrous
materials, such as flax, straw, esparto, bamboo, phormium,
ramie, &c., which on alkaline treatment yield cellulose for
paper-making, and a non-fibrous soluble residue of complex
composition. These soluble derivatives are known as pectin
(C_{32}H_{48}O_{32}), pectic acid (C_{32}H_{44}O_{30}), and
metapectic acid (C_{32}H_{28}O_{36}). Although the soluble
constituents of the pecto-celluloses amount to 50 per cent. by
weight in most cases, no process for the recovery of the product
in a commercial form has yet been devised. (See description of
Soda recovery, page 78.)
PYROXYLINE.--A substance prepared by nitrating cotton. The cotton is
immersed in a mixture of nitric and sulphuric acids of carefully
regulated strength, and subsequently washed free of the acid.
Three volumes of nitric acid (sp. gr. 1·429) are diluted with
two volumes of water and nine volumes of strong sulphuric acid
(sp. gr. 1·839) added. To the solution when cool the cotton is
added in small quantities at a time. The resultant pyroxyline
is soluble in a mixture of equal quantities of alcohol and
ether, and in the soluble form is utilised as _collodion_ for
photography.
SILK, ARTIFICIAL.--A remarkable substance made from wood or cotton
cellulose, closely resembling silk in appearance and physical
properties.
Nitrated cellulose is dissolved in a mixture of equal parts of
alcohol and ether.
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