The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-MakingSindall, R. W. (Robert Walter)
History
The Manufacture of Paper: With Illustrations, and a Bibliography of Works Relating to Cellulose and Paper-Making
Sindall, R. W. (Robert Walter)
Papermaking
The practical operations necessary for the preparation of the size are
comparatively simple. In the case of size containing relatively small
percentages of free rosin, the boiling is conducted in open vessels,
but for the manufacture of rosin size containing large proportions of
free rosin boiling under pressure in closed vessels must be resorted to.
With the open pan process a steam jacketed pan is used, and the
required quantity of alkali, dissolved in water, is placed therein and
heated to boiling point. The rosin well powdered is added in small
quantities from time to time, this being effected cautiously in order
that the carbonic acid gas set free during the process may readily
escape. The rosin is generally completely saponified after four or five
hours' boiling. It is then passed through strainers into store tanks,
from which it is drawn into the beating engines as required.
In the case of rosin boiled under pressure a cylindrical vessel
provided with a manhole at the top is used. The correct amounts of
alkali and water are put into the digester, and also the rosin in a
powdered form, the digester being fitted with a perforated plate placed
about two feet above the bottom of the vessel in order to prevent the
rosin forming into a hard mass at the bottom of the digester.
It is possible in this way to manufacture a thick size containing 30
or 40 per cent. of free rosin and a comparatively small proportion of
water. Many paper mill firms prefer to purchase such size ready made.
The most recent modification of the ordinary rosin size is a compound
prepared by treating rosin with silicate of soda. This alkali dissolves
rosin readily, and the soap obtained when suitably diluted with
water decomposes in the beating engine on the addition of aluminium
sulphate, with the precipitation of a gelatinous silica which assists
in hardening the paper.
Bacon has patented a process in which powdered rosin is melted down
with dry crystalline silicate of soda. The resultant product is ground
to a fine powder, which is then ready for use. It dissolves easily in
water, and when decomposed with the proper proportion of alum gives a
gelatinous viscous mass said to have excellent sizing properties.
The advantages of a dry powdered rosin size readily soluble in water
are obvious.
_Loading._--The term "loading" is applied to the various substances
which are employed for the purpose, as it is commonly supposed, of
making paper heavy. But china clay and similar materials are not added
simply in order to give weight to the paper, since they serve to
produce opacity and to improve the surface of papers which could not be
satisfactorily made unless such materials were used.
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