Until recently it was generally believed that diffusion took place in
colloids and plasmas just as in pure water. This is, however, by no means
the case: the differences are considerable. When a solute is introduced
into a colloidal solution, the greater the concentration of the colloid the
slower will be the diffusion. This may be shown by a simple experiment.
Several glass plates are prepared, by spreading on each a solution of
gelatine of different concentration, to which a few drops of phenol
phthalein have been added. If now a drop of an alkaline solution be placed
on each plate, we can see that the drop diffuses more slowly through the
more concentrated gelatine solution, since the presence of the alkali is
rendered visible by the coloration of the phenol phthalein. A similar
demonstration may be made by allowing drops of acid to diffuse through
solutions of gelatine made slightly alkaline and coloured with phenol
phthalein. In general, we find on experiment that when similar drops of any
coloured or colouring solution are left for an equal time on plates of
gelatine of different degrees of concentration, the greater the
concentration of the gelatine the smaller will be the circle of coloration
obtained.
We may show that the rapidity of diffusion diminishes as the gelatinous
concentration increases, by another experiment. If we put side by side on
our gelatine plate a drop of sulphate of copper and another of ferrocyanide
of potassium, the point of contact of the two fluids will be sharply marked
by a line of precipitate. We find that under similar conditions the time
between the sowing of the drops and the formation of this line of
precipitate is longer when the gelatine is more concentrated.
_Osmosis._--In 1748, l'Abbe Nollet discovered that when a pig's bladder
filled with alcohol was plunged into water, the {45} water passed into the
bladder more rapidly than the alcohol passed out; the bladder became
distended, the internal pressure increased, and the liquid spirted out when
the bladder was pricked by a pin. This passage of certain substances in
solution through an animal membrane is called Osmosis, and membranes which
exhibit this property are called osmotic membranes.
_Precipitated Membranes._--In 1867, Traube of Breslau discovered that
osmotic membranes could be made artificially. Certain chemical precipitates
such as copper ferrocyanide can form membranes having properties analogous
to those of osmotic membranes. With these precipitated membranes Traube
made a number of interesting experiments. These have lately been collected
in the volume of his memoirs published by his son.
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