The Molecular Tactics of a CrystalKelvin, William Thomson, Baron
Science
The Molecular Tactics of a Crystal
Kelvin, William Thomson, Baron
Crystallography, Mathematical
§ 16. Confining our attention for a short time to the homogeneous
division of a plane, remark that the division into parallelograms
by two sets of crossing parallels is singular in this respect--each
cell is contiguous with three neighbours at every corner. Any
shifting, large or small, of the parallelograms by relative sliding
in one direction or another violates this condition, brings us to
a configuration like that of the faces of regularly hewn stones in
ordinary bonded masonry, and gives a partitioning which fulfils the
condition that at each corner each cell has only two neighbours. Each
cell is now virtually a hexagon, as will be seen by the letters _A_,
_B_, _C_, _D_, _E_, _F_ in the diagram Fig. 8. _A_ and _D_ are to be
reckoned as corners, each with an interior angle of 180°. In this
diagram the continuous heavy lines and the continuous faint lines
crossing them show a primitive parallelogrammatic partition by two sets
of continuous parallel intersecting lines. The interrupted crossing
lines (heavy) show, for the same homogeneous distribution of single
points or molecules, the virtually hexagonal partitioning which we get
by shifting the boundary from each portion of one of the light lines to
the heavy line next it between the same continuous parallels.
[Illustration: FIG. 8.]
Fig. 8 bis represents a further modification of the boundary by
which the 180° angles _A_, _D_, become angles of less than 180°. The
continuous parallel lines (light) and the short light portions of the
crossing lines show the configuration according to Fig. 8, from which
this diagram is derived.
§ 17. In these diagrams (Figs. 8 and 8 bis) the object enclosed
is small enough to be enclosable by a primitive parallelogrammatic
partitioning of two sets of continuous crossing parallel straight
lines, and by the partitioning of ‘bonded’ parallelograms both
represented in Fig. 8, and by the derived hexagonal partitioning
represented in Fig. 8 bis, with faint lines showing the primitive and
the secondary parallelograms. In Fig. 7 the objects enclosed were
too large to be enclosable by any rectilinear parallelogrammatic
or hexagonal partitioning. The two sets of parallel faint lines in
Fig. 7 show a primitive parallelogrammatic partitioning and the
corresponding pairs of parallel curves intersecting at the corners of
these parallelograms, of which _A_,_B_,_C_,_D_ is a specimen, show a
corresponding partitioning by curvilineal parallelograms. Fig. 9 shows
for the same homogeneous distribution of objects a better conditioned
partitioning, by hexagons in each of which one pair of parallel
edges is curved. The sets of intersecting parallel straight lines in
Fig. 9 show the same primitive parallelogrammatic partitioning as
in Fig. 7, and the same slightly shifted to suit points chosen for
well-conditionedness of hexagonal partitioning.
[Illustration: FIG. 8 bis.]
[Illustration: FIG. 9.]
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