The Monist, Vol. 3, 1892-1893 : $b A quarterly magazine — John Shaqi
The Monist, Vol. 3, 1892-1893 : $b A quarterly magazineVarious
Philosophy
The Monist, Vol. 3, 1892-1893 : $b A quarterly magazine
Various
Philosophy -- Periodicals
I cannot assume that the students of philosophy who read this magazine
are thoroughly versed in modern molecular physics, and therefore it
is proper to mention that the governing principle in this branch of
science is Clausius’s law of the virial. I will first state the law,
and then explain the peculiar terms of the statement. This statement is
that the total kinetic energy of the particles of a system in stationary
motion is equal to the total virial. By a _system_ is here meant a
number of particles acting upon one another.[5] Stationary motion is a
quasi-orbital motion among a system of particles so that none of them are
removed to indefinitely great distances nor acquire indefinitely great
velocities. The kinetic energy of a particle is the work which would
be required to bring it to rest, independently of any forces which may
be acting upon it. The virial of a pair of particles is half the work
which the force which actually operates between them would do if, being
independent of the distance, it were to bring them together. The equation
of the virial is
(Transcriber’s Note: Italics have been removed from the
formulæ for readability.)
½Σmv² = ½ΣΣRr.
Here _m_ is the mass of a particle, _v_ its velocity, _R_ is the
attraction between two particles, and _r_ is the distance between them.
The sign Σ on the left hand side signifies that the values of _mv_²
are to be summed for all the particles, and ΣΣ on the right hand side
signifies that the values of _Rr_ are to be summed for all the pairs of
particles. If there is an external pressure _P_ (as from the atmosphere)
upon the system, and the volume of vacant space within the boundary of
that pressure is _V_, then the virial must be understood as including
³⁄₂_PV_, so that the equation is
½Σmv² = ³⁄₂PV + ½ΣΣRr.
There is strong (if not demonstrative) reason for thinking that
the temperature of any body above the absolute zero (-273° C.), is
proportional to the average kinetic energy of its molecules, or say _aθ_,
where _a_ is a constant and _θ_ is the absolute temperature. Hence, we
may write the equation
aθ = ½m̅v̅²̅ = ³⁄₂PV̅ + ½ΣR̅r̅
where the heavy lines above the different expressions signify that the
average values for single molecules are to be taken. In 1872, a student
in the University of Leyden, Van der Waals, propounded in his thesis for
the doctorate a specialisation of the equation of the virial which has
since attracted great attention. Namely, he writes it
aθ = (P + (c⁄V²))(V-b).
Public-domain text, read in full here on John Shaqi.
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