The natural and artificial disintegration of the elements: An address by Professor Sir Ernest RutherfordRutherford, Ernest
Science
The natural and artificial disintegration of the elements: An address by Professor Sir Ernest Rutherford
Rutherford, Ernest
Atoms; Chemical elements; Radioactivity
In considering the origin of the elements, we may for simplicity suppose
a large diffused mass of hydrogen which is gradually heated by its
gravitational condensation. At high temperatures the gas would consist
mainly of free hydrogen nuclei and electrons, and some of these would in
course of time combine to form neutrons, emitting energy in the process.
These neutrons would collect together in nuclear masses of all kinds of
complexity. Now the tendency of the groups of neutrons would be to form
more stable nuclear combinations, such as helium nuclei of mass four,
and possibly intermediate stages of masses two and three. Energy would
be emitted in these processes probably in the form of swift surplus
electrons which were not necessary for the stability of the system. In a
sense, all these nuclear masses would be radioactive, but some of them
in their transformation may reach a stable configuration which would
represent the nucleus of one of our surviving elements. If we suppose
that nuclear masses over a wide range of mass can be formed before
serious transformation occurs, it is easy to see how every possible type
of stable element will gradually emerge. If we take the helium nucleus
as a combining unit which emits in its formation the greatest amount of
energy, we should ultimately expect many of the neutrons in a heavy
nucleus to form helium nuclei. These helium nuclei would tend to collect
together and form definite systems and it seems not unlikely that they
will group themselves into orderly structures, analogous in some
respects to the regular arrangement of atoms to form crystals, but with
much smaller distances between the structural units. In such a case,
some of the elements may consist of a central crystal type of structure
of helium nuclei surrounded by positive and negatively charged
satellites in motion round this central core. Assuming that such orderly
arrangements of helium nuclei are possible, it is of interest to note
that the observed relations between atomic charge and atomic mass for
the elements can be approximately obtained on a very simple assumption.
Suppose that helium nuclei form a point centred cubic lattice with an
electron at the centre of a crystal unit of eight helium nuclei. A few
of the possible types of grouping are given in the following table, with
corresponding masses and nuclear charges. The structure 4. 3. 2. means
a rectangular arrangement with sides containing 4. 3. 2. nuclei
respectively. It will thus contain 24 helium nuclei, have a mass 96, and
will contain 6 intranuclear electrons. Its nuclear charge will therefore
be 48 - 6 = 41.
Structural arrangement of Calculated Calculated Known element of
helium nuclei nuclear charge Mass equal charge
3. 2. 2. 22 48 Ti 48
3. 3. 2. 32 72 Ge 74, 72, 70
3. 3. 3. 46 108 Pd 106.7
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