The Natural History of ClaySearle, Alfred B. (Alfred Broadhead)
Science
The Natural History of Clay
Searle, Alfred B. (Alfred Broadhead)
Clay
Kaolins are seldom found in a sufficiently pure state to be used direct,
but must be freed from large amounts of undecomposed rock, quartz, mica,
etc., by a process of washing and sedimentation. When purified in this
manner, the best qualities of china clay yield, on analysis, alumina,
silica and water in the proportions indicated by the formula
H4Al2Si2O9 together with about 5 per cent. of mica and other
impurities. Some high class commercial kaolins contain over 30 per cent.
of mica and 10 per cent. of quartz.
The chief constituents of rocks which take part in the production of
kaolins appear to be the felspars, but the natural processes by which
these felspars are decomposed are by no means perfectly understood. Some
kaolins appear to have been formed by weathering and others by subaerial
action. Thus Collins (19) has stated very emphatically that the
kaolinization of Cornish felspar has been chiefly effected by fluorine
and other substances rising from below and not by carbonic acid and
water acting from above. Ries (6) and other American observers are
equally convinced that certain kaolins they have examined are the result
of 'weathering.' German and French investigators are divided in their
opinions, and Fuchs has found that the Passau (Saxony) kaolin is derived
from a special mineral, not unlike a soda-lime felspar deficient in
silica, to which he has given the name 'porcelain spar.'
The _felspars_ form a class of minerals whose chief characteristic is
the combination of an alkaline or alkaline-earth base with silica and
alumina. Orthoclase (K2OAl2O3·6SiO2)--the chief potassium
felspar--is typical of the whole class. When treated with water under
suitable conditions, the felspar appears to become hydrolysed and some
of the water enters into combination, the potash being removed by
solution. Attempts to effect this decomposition artificially have proved
abortive though several investigators appear to have effected it to a
limited extent by electrolysis or by heating under great pressure (3).
The effect on felspars of waters containing carbon dioxide in solution
has been studied by Forschammer, Vogt, and others, and they have
concluded that kaolinization may occur with this agent though it does
not appear to be the chief cause in the formation of Cornish china
clays.
[Illustration: Fig. 13. Orthoclase Felspar, natural size. (_From Miers_'
Mineralogy _by permission of Macmillan & Co._)]
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